“…The WCA and UOWCA of SSM, CA coatings without MTCS deposited (C‐5), and CA coatings with MTCS deposited but different in electrostatic spraying times (C‐5‐M to C‐60‐M) are shown in Figure 4B,C. The contact angles of all CA coating samples are almost always above 154°, which is better than those reported in several papers that have been reported 10,27 . This confirms the superhydrophobic properties of the CA coating under air and oil for electrostatic spraying combined with vapor deposition of MTCS.…”
Section: Resultssupporting
confidence: 68%
“…Figure 6B illustrates the separation fluxes of C‐60‐M for six different oil compounds and organic‐like solvents, which are ranging from 18644.44 to 23977.77 L·m −2 ·h −1 . The separation efficiencies were all above 99%, which are better than those reported in several papers that have been reported 27–29 . Table 1 is a list of some of the recent research work with reference to this work.…”
Section: Resultsmentioning
confidence: 63%
“…The contact angles of all CA coating samples are almost always above 154 , which is better than those reported in several papers that have been reported. 10,27 This confirms the superhydrophobic properties of the CA coating under air and oil for electrostatic spraying combined with vapor deposition of MTCS. The WCA of the SSM is 122.66 , CA is hydrophilic due to the presence of a certain amount of hydroxyl groups, but the results of the water contact angle of C-5 in Figure 4B show that even without the deposition of the "water-repellent" MTCS, the value remains above 150 , which is superhydrophobic.…”
Section: Surface Wettabilitymentioning
confidence: 52%
“…The separation efficiencies were all above 99%, which are better than those reported in several papers that have been reported. [27][28][29] Table 1 is a list of some of the recent research work with reference to this work. Figure 6C presents the results of a 50-cycle separation experiment using the C-60-M. shown in Figure 6C, the separation flux slightly decreases with an increasing number of separations.…”
The efficient and simple separation of oil–water mixtures has been a global challenge due to the growing problem of oily wastewater. To address this issue, various materials with special wetting properties and functionality have been developed in the past decades for oil–water separation. In this study, a superhydrophobic cellulose acetate (CA) functional coating was prepared by electrostatic spraying of CA and chemical vapor deposition of methyltrichlorosilane (MTCS) on a stainless steel mesh (SSM). Water contact angle in air (WCA) of the resulting coating is154° or more, and oil under water contact angle (UWOCA) is 0°. Simultaneously, the separation flux of the resulting coating for oil–water mixtures is as high as 23977.77 L·m−2·h−1, with separation efficiencies exceeding 99%. Due to its excellent water repellency, the CA functional coating can effectively separate oil and water, and can be easily dried for continuous use. Furthermore, the CA functional coating exhibits good stability in salt solutions and acidic environments, making it an ideal material for addressing oily wastewater challenges.Highlights
The coating obtained by electrostatic spraying and CVD was superhydrophobic.
The separation flux and separation efficiencies of coatings is 23977.77 L·m−2·h−1 and 99%.
Coatings remain stable under polar environment conditions (pH = 2–12 and NaCl = 1–3 mol/L).
“…The WCA and UOWCA of SSM, CA coatings without MTCS deposited (C‐5), and CA coatings with MTCS deposited but different in electrostatic spraying times (C‐5‐M to C‐60‐M) are shown in Figure 4B,C. The contact angles of all CA coating samples are almost always above 154°, which is better than those reported in several papers that have been reported 10,27 . This confirms the superhydrophobic properties of the CA coating under air and oil for electrostatic spraying combined with vapor deposition of MTCS.…”
Section: Resultssupporting
confidence: 68%
“…Figure 6B illustrates the separation fluxes of C‐60‐M for six different oil compounds and organic‐like solvents, which are ranging from 18644.44 to 23977.77 L·m −2 ·h −1 . The separation efficiencies were all above 99%, which are better than those reported in several papers that have been reported 27–29 . Table 1 is a list of some of the recent research work with reference to this work.…”
Section: Resultsmentioning
confidence: 63%
“…The contact angles of all CA coating samples are almost always above 154 , which is better than those reported in several papers that have been reported. 10,27 This confirms the superhydrophobic properties of the CA coating under air and oil for electrostatic spraying combined with vapor deposition of MTCS. The WCA of the SSM is 122.66 , CA is hydrophilic due to the presence of a certain amount of hydroxyl groups, but the results of the water contact angle of C-5 in Figure 4B show that even without the deposition of the "water-repellent" MTCS, the value remains above 150 , which is superhydrophobic.…”
Section: Surface Wettabilitymentioning
confidence: 52%
“…The separation efficiencies were all above 99%, which are better than those reported in several papers that have been reported. [27][28][29] Table 1 is a list of some of the recent research work with reference to this work. Figure 6C presents the results of a 50-cycle separation experiment using the C-60-M. shown in Figure 6C, the separation flux slightly decreases with an increasing number of separations.…”
The efficient and simple separation of oil–water mixtures has been a global challenge due to the growing problem of oily wastewater. To address this issue, various materials with special wetting properties and functionality have been developed in the past decades for oil–water separation. In this study, a superhydrophobic cellulose acetate (CA) functional coating was prepared by electrostatic spraying of CA and chemical vapor deposition of methyltrichlorosilane (MTCS) on a stainless steel mesh (SSM). Water contact angle in air (WCA) of the resulting coating is154° or more, and oil under water contact angle (UWOCA) is 0°. Simultaneously, the separation flux of the resulting coating for oil–water mixtures is as high as 23977.77 L·m−2·h−1, with separation efficiencies exceeding 99%. Due to its excellent water repellency, the CA functional coating can effectively separate oil and water, and can be easily dried for continuous use. Furthermore, the CA functional coating exhibits good stability in salt solutions and acidic environments, making it an ideal material for addressing oily wastewater challenges.Highlights
The coating obtained by electrostatic spraying and CVD was superhydrophobic.
The separation flux and separation efficiencies of coatings is 23977.77 L·m−2·h−1 and 99%.
Coatings remain stable under polar environment conditions (pH = 2–12 and NaCl = 1–3 mol/L).
“…It has been shown that through the adsorption between the hydroxyl radicals on the surface of the carbon sphere template and the oxygen-containing functional groups and the metal cations, a layer of metal cations can be formed on the carbon sphere template, after which the carbon sphere template is removed by roasting at a certain temperature, and a metal hollow sphere is prepared. [16][17][18][19] However, the method has certain drawbacks in which there is limited adsorption between the oxygen-containing functional groups on the surface of the carbon sphere template and the metal cations, resulting in the formation of very thin shells of hollow microspheres that are prone to collapse. [20][21][22][23][24] Zirconium dioxide is the only metal oxide that is simultaneously acidic, basic, oxidizing and reducing and is a p-type semiconductor material that readily generates oxygen vacancies and interacts with active components as a catalyst carrier.…”
Membranes with superhydrophobicity have attracted much attention in recent years for improving self‐cleaning in practical applications. In this study, highly‐adhesion hydrophobic membranes and superhydrophobic membranes were prepared and used for preciously rare droplets transportation and efficient oil‐water separation separately. The two types of membranes with different applications were prepared by electrospinning and the morphology and structures of the electrospinning membranes were adjusted by regulating serious of parameters including voltage, flow rate and the diameter of the spinning needle. The as‐prepared membranes with apparent superhydrophobicity were fluorine‐free, environmentally friendly materials and realised effective and rapid oil‐water separation; moreover, the membranes exhibit excellent adhesivity when measured by the video‐optical contact angle system, and the maximum adhesion amount was 80 μL. The two membranes reported here were easily fabricated and reproducible, with adhesive and superhydrophobic properties, respectively. so we envision that the membrane has the potential to be used in a variety of practical applications such as the development of robots that require non‐destructive liquids transportation, efficient oil‐water separators and so on.This article is protected by copyright. All rights reserved.
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