2017
DOI: 10.1038/s41467-017-02093-z
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Van der Waals epitaxial growth and optoelectronics of large-scale WSe2/SnS2 vertical bilayer p–n junctions

Abstract: High-quality two-dimensional atomic layered p–n heterostructures are essential for high-performance integrated optoelectronics. The studies to date have been largely limited to exfoliated and restacked flakes, and the controlled growth of such heterostructures remains a significant challenge. Here we report the direct van der Waals epitaxial growth of large-scale WSe2/SnS2 vertical bilayer p–n junctions on SiO2/Si substrates, with the lateral sizes reaching up to millimeter scale. Multi-electrode field-effect … Show more

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Cited by 394 publications
(339 citation statements)
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References 69 publications
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“…Photodetectors based on direct‐CVD‐grown heterojunctions have been demonstrated . By direct vapor‐phase growth, Li et al fabricated epitaxial vertical SnS 2 /MoS 2 heterostructures with a sharp interface and type‐II band alignment with an extremely large band offset.…”
Section: Strategies For Enhancing the Performance Of Photodetectorsmentioning
confidence: 99%
“…Photodetectors based on direct‐CVD‐grown heterojunctions have been demonstrated . By direct vapor‐phase growth, Li et al fabricated epitaxial vertical SnS 2 /MoS 2 heterostructures with a sharp interface and type‐II band alignment with an extremely large band offset.…”
Section: Strategies For Enhancing the Performance Of Photodetectorsmentioning
confidence: 99%
“…The vertically stacked hetero-structure has been successfully synthesized by a layer-by-layer epitaxial [87], and laterally stacked hetero-structure synthesis method though single-step CVD approaches have also been reported recently (examples illustrated in Figure 4a- Figure 4b, c and d, the domain size is much larger than that of the previously mentioned one-step approach [82]. Similar approaches have been used to grow SnS2/WSe2 heterojunction (Figure 4f,g) [85]. Compared to the manually stacked heterojunctions, the CVD epitaxial method can be evolved into a promising application in optoelectronics devices with a high-quality hetero-structure.…”
Section: Heterojunctionmentioning
confidence: 73%
“…It is possible to control epitaxial orientation with different growth temperatures and as shown in Figure 4b, c and d, the domain size is much larger than that of the previously mentioned one-step approach [82]. Similar approaches have been used to grow SnS 2 /WSe 2 heterojunction (Figure 4f,g) [85]. Compared to the manually stacked heterojunctions, the CVD epitaxial method can be evolved into a promising application in optoelectronics devices with a high-quality hetero-structure.…”
Section: Heterojunctionmentioning
confidence: 97%
“…The illustration is an optical image of a heterojunction device. Reproduced with permission . Copyright 2017, Springer Nature.…”
Section: Low‐dimensional Semiconductor Nanomaterialsmentioning
confidence: 99%
“…Optimizing the performance of PDs by heterojunction is an effective method. For example, PDs are constructed using directly grown vertical double‐layer WSe 2 /SnS 2 p‐n structures (Figure D) This parallel‐series mode device exhibits significant changes compared with the original structure (Table ). This van der Waals heterostructure can further adjust the electrical and optical properties of the device by coupling between layers …”
Section: Promising Applications Of Low‐dimensional Semiconductor Matementioning
confidence: 99%