1973
DOI: 10.1016/s0022-328x(00)84996-7
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19F substituent chemical shifts of the fluorophenyldiphenylsilanes and the carbon analogs

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Cited by 10 publications
(2 citation statements)
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“…145 Central to the problem of relating chemical shifts for aliphatic systems to electronic effects (supposing that perturbing factors can be allowed for) is the nature of the inductive effect itself. For correlations for aromatic compounds only a dipole-field effect (including 7r polarization) is important (four or more bonds between probe nucleus and substituent).…”
Section: Aliphatic Compoundsmentioning
confidence: 99%
“…145 Central to the problem of relating chemical shifts for aliphatic systems to electronic effects (supposing that perturbing factors can be allowed for) is the nature of the inductive effect itself. For correlations for aromatic compounds only a dipole-field effect (including 7r polarization) is important (four or more bonds between probe nucleus and substituent).…”
Section: Aliphatic Compoundsmentioning
confidence: 99%
“…In addition, treatment of 5e (R 2 = p ‐FC 6 H 4 ) with SnCl 4 (1.5 mol) in benzene at R.T. afforded an unexpected triarylmethane 9e (R 2 = p ‐FC 6 H 4 ) in 12% yield besides a complex mixture. Furthermore, the similar reaction of 5e with SnCl 4 carried out in CH 2 Cl 2 in the presence of an excess amount of allyltrimethylsilane at –78°C afforded unstable Te ‐allyl N,N ‐diethyltellurocarbamate ( 10 ) in 12% yield besides several uncharacterized products.…”
Section: Resultsmentioning
confidence: 99%