2 Photoemission electron microscopy (PEEM) and energy filtered X-ray PEEM (EXPEEM) are reviewed. PEEM enables the in situ observation of surface chemical phenomena resolved in space and time. In order to achieve surface chemical imaging, excitation at the core level is preferable and a combination of PEEM and X-ray photoelectron spectroscopy is necessary which has been realized by the EXPEEM. We review in particular an EXPEEM installed with a Wien filter energy analyzer are reviewed. Examples of the practical application of PEEM and EXPEEM to surface chemistry are presented.
AbstractThis chapter reviews photoemission electron microscopy(PEEM) and energy filtered X-ray PEEM (EXPEEM) that provides us the chemical mapping of the surface. We describe the history and the principle of PEEM and EXPEEM. We focus on the Wien filter type energy The surface is illuminated by a UV lamp and photoelectrons are ejected from the surface, depending on the local work function. The work function of O 2 is larger than CO and the amount of electrons coming from the O 2 -adsorbed surface becomes smaller; therefore, the dark and bright regions correspond to the O 2 and CO adsorbed domains, respectively. PEEM had revealed that surface reactions are inhomogenous, even on a single crystal and in situ surface microscopy is necessary since the pattern is formed under reaction conditions.The PEEM image in Fig. 1 shows the distribution of O 2 and CO that can be obtained only by their different work functions when they are adsorbed on a surface. Therefore, PEEM can not 3 be applied to complex systems where the work functions of the reaction components are not so easily distinguished. However, PEEM has the following advantages: 1) less specimen damage than conventional electron microscopy, and 2) versatility to provide physical and chemical information by the selection of excitation photon sources.
2,3In contrast to transmission electron microscopy (TEM) or scanning electron microscopy (SEM), PEEM requires a photon source that has a small interaction with matter, resulting in minimal sample damage. The second advantage is related to the photoemission mechanism of PEEM. Although the amount of photoelectrons excited by a simple UV light source is simply related to the work function of the surface, 3 the number of excited photoelectrons depends on the local magnetism of the surface when circularly or linearly polarized light is used. 4,5 X-rays excite the core electrons, which contain chemical information. Synchrotron radiation 6 is an energy-tunable X-ray source, which can be used to obtain chemically-sensitive PEEM images when the X-ray energy is set near the absorption edge energy. On the other hand, kinetic energy analysis of the photoelectrons is necessary to obtain chemically sensitive PEEM images for a constant photon energy source such as conventional Bremsstrahlung X-rays. PEEM combined with photoelectron energy analysis is referred to as an energy filtered X-ray PEEM (EXPEEM).
7-13One challenging aspect is the weak photoelectron peak si...