1,4-bis[2,2-bis(trimethylsilyl)ethenyl]benzene: Regioselective ring opening of its α,β-epoxybis(silane) with some nucleophiles

Facile route to synthesis of functionalised poly(methylalkoxy)siloxane under mild and aerobic conditions in the presence of platinum catalysts

“…As a part of our continuing research on the organosilicon chemistry [19][20][21][22][23][24], we have particularly been interested in developing the alcoholysis reaction between PMHS and various simple and functional alcohols. The objective of this research is the preparation of novel and functional poly(methylalkoxysiloxane) in mild conditions and high yield approach in the presence of Speier's and Karstedt's catalyst.…”

Synthesis of new organosilicon compounds by CS2: Mercapto-silyl-thiones

“…The resulting product (1) shows that the migration of sulphur to carbon of C(SiMe 3 ) 2 has been occurred. It seems likely that the obtained product (1) forms through the intermediates 1de1g and after hydrolysis of 1g (Scheme 2).…”

Synthesis of organosilyl compounds-containing 1,2,4,5-tetraaryl imidazoles sonocatalyzed by M/SAPO-34 (M = Fe, Co, Mn, and Cu) nanostructures

“…Cu/SAPO-34 We have recently used bulky tris(trimethylsilyl)-methyllithium (TsiLi) as a reagent for the preparation of vinylsilanes, epoxysilanes, halovinylsilanes, silyl ethers, etc. [25][26][27][28][29][30]. In the previous publication, we reported the synthesis of bulky organosilicon groups containing highly substituted imidazoles using silyl-substituted organometallic reagents (RSiMe 2 ) 3 CLi (R = H, Me, Ph) [31,36].…”