High selectivities (>20) for dry etching of In 0.49 Ga 0.51 P over Al 0.5 In 0.5 P are found over a wide range of conditions in inductively coupled plasmas using BI 3 and BBr 3 . The etch stop mechanism appears to be the formation of relatively involatile AlI x and AlBr x species. Selectivities of ≥8 for InGaP over common mask materials SiO 2 and SiN x are obtained with both chemistries. © 1998 The Electrochemical Society, Inc. S1099-0062(97)12-096Manuscript submitted January 12, 1998; revised manuscript received March 22, 1998. The In 0.49 Ga 0.51 P/Al 0.5 In 0.5 P heterostructure is lattice matched to GaAs, making it useful as a replacement for AlGaAs/GaAs in high electron mobility transistors, heterojunction bipolar transistors, and visible light emitting diodes and lasers. [1][2][3][4][5][6][7][8][9][10] In developing device fabrication processes it is necessary to have wet and dry etches that are highly selective for one material over another. For the InGaP/GaAs and AlInP/GaAs systems, Lothian et al. 11,12 reported such recipes previously. However, there has been little work on selective dry etches for the InGaP/AlInP system. In nonselective etching it is possible to use Cl 2 /CH 4 /H 2 /Ar discharges under high density plasma conditions. 13 Chlorine-based plasma chemistries such as Cl 2 /Ar, BCl 3 /Ar, or BCl 3 /N 2 do not provide much etch selectivity for InGaP/AlInP. 14,15 Little work has been done on alternative chemistries such as those based on I 2 or Br 2 .1 6,17 In this paper, we show that two new plasma chemistries for etching compound semiconductors, namely, BI 3 and BBR 3 , provide excellent selectivities for InGaP over AlInP under inductively coupled plasma (ICP) conditions. We have measured this selectivity as a function of plasma composition and high density source power, and also measured the selectivity of InGaP over two common masking materials, SiO 2 and SiN x .The InGaP and AlInP layers were grown lattice matched to undoped, (100) GaAs substrates by metallorganic molecular beam epitaxy (MOMBE) 18 or metallorganic chemical vapor deposition (MOCVD). 19 The layers were nominally undoped (n ~ 3 ؋ 10 16 cm -3 ). Etching was performed in a Plasma Therm 790 reactor, in which the plasma is generated in a three-turn ICP source operating at 2 MHz and powers up to 1000 W. Samples were thermally bonded to a Si carrier wafer, which was mechanically clamped to an rf-powered (13.56 MHz, 150-450 W) He back side cooled chuck. The process pressure was held constant at 5 mTorr. Approximately 50 g of either BI 3 (mp 44°C) or BBr 3 (bp 91.2°C) was placed in a quartz container inside a stainless steel vacuum vessel heated to ~45°C to increase the vapor pressure of the reactants. The resultant vapors were injected into the ICP source through electronic mass flow controllers at rates up to 10 standard cubic centimeters per minute (sccm). Argon was typically mixed in with the BI 3 or BBr 3 to assist plasma ignition. Etch rates were measured by stylus profilometry of patterned features. Figure 1 shows etch rate...