Petroleum-based adhesive resins have extensively been used for the production of wood panels. However, it is necessary to develop environmentally friendly adhesive resins due to the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the pertroleum-based adhesive resins. This study was conducted to formulate environmentally friendly adhesive resins using by rapeseed flour (RSF), which is the by-product of bio-diesel produced from rapeseed, for replacing petroleum-based adhesives with them. To formulate RSF-based adhesive resins, RSF was hydrolyzed in de-ionized water, 1% and 3% sodium hydroxide solutions. As a crosslinking agent, PF prepolymers were prepared with 1.8, 2.1 and 2.4 mol formaldehyde and 1 mol phenol (1.8-, 2.1-and 2.4-PF), and then mixed with RSF hydrolyzates to complete the formulation of RSF-based adhesive resins. The RSF-based adhesive resins were applied to fabricate 3-ply plywood panels. The solid content of RSF-based adhesive resins were ranged from 26.08% to 36.12% depending on the hydrolysis condition of RSF and PF prepolymer type with a high viscosity. The tensile shear strength and wood failure of plywood fabricated with RSF-based adhesive resins exceeded a minimum requirement of KS standard for ordinary plywood regardless of the hydrolysis condition of RSF and PF prepolymer type.Formaldehyde emissions of the plywood panels fabricated with 1.8-PF and RSF hydrolyzates were lower than that of E0 specified in the KS standard. Based on the results, RSF might be used as a raw material of environmentally friendly adhesives for the production of plywood panels, but further researches -the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure -are required to commercialize the RSF-based adhesives.
The aim of this paper is to present the modulus of elasticity of E L , E R , E T along three principal axis of softwood dimension lumber by nondestructive method. Ultrasonic measurement was carried out on defect free wood samples taken by the Japanese Larch, SPF (spruce-pine-fir) and Hem-fir 2 × 4 s. The ultrasound velocities were measured to calculate young's moduli and it was derived elastic constants for each wood samples using the ultrasound velocities and densities of wood. From the test, E L was much greater than E R and E T . E R /E T ratios were about 1.3. The high density wood had high young's moduli in three principal axis and the difference in young's moduli between species was greater in transverse direction than longitudinal direction. The anisotropy of the lumber was presented through the calculated elastic moduli and compliances matrix in diagonal term were determined by inverting the stiffness matrix.
Manufacture and Performance Evaluation of Medium-densityFiberboard Made with Coffee Bean Residue-Wood Fiber* 1In Yang* 2 ⋅Kwang-hyung Lee* 3 ⋅Sei-chang Oh* 4 † 요 약
In the present study, rapeseed flour (RSF), which is a by-product from the production of edible oil and biodiesel extracted from rapeseed, was used to develop alternative adhesives for the production of plywood panels. To examine the effects of the enzyme on the adhesive properties and formaldehyde emission of the RSF-based adhesive resins, three enzymes, such as cellulase (CEL), pectinase (PEC) and protease (ALC), were used either separately or together. As a crosslinking agent, PF prepolymers, which were prepared with 1.5, 1.8 and 2.1 mole formaldehyde and 1 mol phenol (1.8-, 2.1-and 2.4-PF), were added into the RSF hydrolyzates. The adhesive resins formulated with CEL-or CEL-PEC-RSF hydrolyzates and 1.8-F/P PF prepolymers exhibited excellent adhesive strengths and formaldehyde emission. The tensile shear strength and formaldehyde emission of the plywood panels bonded with the formulate resins were satisfied with the minimum requirement of the KS standard for ordinary plywood panels (0.6 N/mm 2 ). In addition, formaldehyde emissions of the plywood panels approached to that of E0 specified in the KS standard (0.5 mg/ℓ), and even had much better than those of commercial UF glue mixes. Overall, the use of RSF-based adhesive resins for the production of plywood panels might provide durable adhesive properties and an environmentally friendly substitute for petroleum-based adhesive resins. However, further researches -the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure -are required to commercialize the RSF-based adhesives.
Annual average daily traffic(AADT) serves as important basic data in the transportation sector. AADT is used as design traffic which is the basic traffic volume in transportation planning. Despite of its importance, at most locations, AADT is estimated using short term traffic counts. An accurate AADT is calculated through permanent traffic counts at limited locations. This study dealt with estimating AADT using various models considering both the spatial correlation and time series data. Kriging models which are commonly used spatial statistics methods were applied and compared with each model. Additionally the External Universal kriging model, which includes explanatory variables, was used to assure accuracy of AADT estimation. For evaluation of various kriging methods, AADT estimation error, proposed using national highway permanent traffic count data, was analyzed and their performances were compared. The result shows the accuracy enhancement of the AADT estimation.
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