We present the radio properties of optically selected quasars with z ≥ 3. The complete sample consists of 102 quasars with a flux density level S1.4 ≥ 100 mJy in a declination range −35° ≤ Dec. ≤ +49°. The observations were obtained in 2017–2020 using the radio telescope RATAN-600. We measured flux densities at six frequencies 1.2, 2.3, 4.7, 8.2, 11.2, and 22 GHz quasi-simultaneously with uncertainties of 9–31 per cent. The detection rate is 100, 89, and 46 per cent at 4.7, 11.2, and 22 GHz, respectively. We have analysed the averaged radio spectra of the quasars based on the RATAN and literature data. We classify 46 per cent of radio spectra as peaked-spectrum, 24 per cent as flat, and none as ultra-steep spectra (α ≤ −1.1). The multifrequency data reveal that a peaked spectral shape (PS) is a common feature for bright high-redshift quasars. This indicates the dominance of bright compact core emission and the insignificant contribution of extended optically thin kpc-scale components in observed radio spectra. Using these new radio data, the radio loudness log  R was estimated for 71 objects with a median value of 3.5, showing that the majority of the quasars are highly radio-loud with log  R > 2.5. We have not found any significant correlation between z and α. Several new megahertz- peaked spectrum (MPS) and gigahertz- peaked spectrum (GPS) candidates are suggested. Further studies of their variability and additional low-frequency observations are needed to classify them precisely.

Gigahertz-Peaked spectrum (GPS) sources are compact active galactic nuclei, presumably young precursors of bright radio sources. The study of GPS radio properties provides information about the features of synchrotron radiation in extragalactic sources. Also in applied research GPS sources are useful as compact stationary radio sources in the sky for astrometric purposes. This paper presents the results of a multifrequency GPS study based on quasi-simultaneous measurements with the RATAN-600 radio telescope during the 2006-2017. The catalog containing spectral flux densities measured at six frequencies (1.1, 2.3, 4.8, 7.7/8.2, 11.2, and 21.7 GHz) have been obtained. In addition, for the analysis of radio spectra, data from the following low-frequency surveys have been used: GLEAM (GaLactic and Extragalactic All-sky Murchison widefield array survey) and TGSS (Tata institute for fundamental research GMRT Sky Survey) and high-frequency measurements from Planck survey. A total number of 164 GPS and candidates to GPS have been identified (17 of them are new discoveries), which makes up a small fraction of GPS in the initial sample of bright AGNs, about 2%. The physical properties and formation conditions of synchrotron radiation is found to be quite different in GPS of different AGN types. The deficit of distant GPS (z > 2) with low maximum frequencies (less than 1 GHz) is confirmed. The existing "size -peak frequency" anticorrelation is continuous. The continuum radio spectra are found to become statistically steeper with increasing redshift.

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BackgroundAttine ants live in symbiosis with a basidiomycetous fungus that they rear on a substrate of plant material. This indirect herbivory implies that the symbiosis is likely to be nitrogen deprived, so that specific mechanisms may have evolved to enhance protein availability. We therefore hypothesized that fungal proteinase activity may have been under selection for efficiency and that different classes of proteinases might be involved.ResultsWe determined proteinase activity profiles across a wide pH range for fungus gardens of 14 Panamanian species of fungus-growing ants, representing eight genera. We mapped these activity profiles on an independently obtained molecular phylogeny of the symbionts and show that total proteinase activity in lower attine symbionts peaks at ca. pH 6. The higher attine symbionts that have no known free-living relatives had much higher proteinase activities than the lower attine symbionts. Their total in vitro proteinase activity peaked at pH values around 5, which is close to the pH that the ants maintain in their fungus gardens, suggesting that the pH optimum of fungal proteinases may have changed after the irreversible domestication of evolutionary more derived fungal symbionts. This notion is also supported by buffering capacities of fungus gardens at pH 5.2 being remarkably high, and suggests that the fungal symbiont actively helps to maintain garden acidity at this specific level. Metalloproteinases dominated the activity profiles of lower attine gardens and may thus represent the ancestral type of proteinase production, whereas serine proteinase activity dominated the activity profiles of the higher attine gardens reared by Trachymyrmex and Sericomyrmex, suggesting that there may be trade-offs in the production of these enzyme classes. Remarkably, the single symbiont that is shared by species of the crown group of Atta and Acromyrmex leaf-cutting ants mostly showed metalloproteinase activity, suggesting that recurrent changes in enzyme production may have occurred throughout the domestication history of fungus-garden symbionts.ConclusionsProteinase pH optima and buffering capacities of fungal symbionts appear to have evolved remarkable adaptations to living in obligate symbiosis with farming ants. Although the functional roles of serine and metalloproteinases in fungus gardens are unknown, the differential production of these classes of proteolytic enzymes suggest that substrate specificity may be important and that trade-offs may prevent the simultaneous upregulation of both classes of enzymes.

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New stable nanocomposites with copper nanoparticles (CuNPs) in a polymer matrix have been synthesized by green chemistry. Non-toxic poly-N-vinylimidazole was used as a stabilizing polymer matrix and ascorbic acid was used as a reducing agent. The polymer CuNPs nanocomposites were characterized by Fourier transform infrared (FTIR) spectroscopy, ultraviolet–visible (UV) spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), atomic absorption spectroscopy (AAS), and thermogravimetric analysis (TGA). It was shown, using the dynamic light scattering (DLS) method, that the hydrodynamic diameters of nanocomposites depend on the CuNPs content and are in an associated state in an aqueous medium. The copper content in nanocomposites ranges from 1.8 to 12.3% wt. The obtained polymer nanocomposites consist of isolated copper nanoparticles with a diameter of 2 to 20 nm with a spherical shape.