The majority of literature sources dedicated to dissimilar Al-Cu friction stir welding testifies to the formation of intermetallic compounds (IMC) according to diffusion-controlled reactions, i.e., without liquation on the Al/Cu interfaces. Fewer sources report on revealing Al-Cu eutectics, i.e., that IMCs are formed with the presence of the liquid phase. This work is an attempt to fill the gap in the results and find out the reasons behind such a difference. Structural-phase characteristics of an in-situ friction stir processed (FSP) Al-Cu zone were studied. The single-pass FSPed stir zone (SZ) was characterized by the presence of IMCs such as Al2Cu, Al2Cu3, AlCu3, Al2MgCu, whose distribution in the SZ was extremely inhomogeneous. The advancing side SZ contained large IMC particles as well as Al(Mg,Cu) solid solution (SS) dendrites and Al-Al2Cu eutectics. The retreating side SZ was composed of Al-Cu solid solution layered structures and smaller IMCs. Such a difference may be explained by different levels of heat input with respect to the SZ sides as well as by using lap FSP instead of the butt one.
WC-(Fe-Mn-C) composites with γ-iron and γ + α’ matrices were sintered and then tested at sliding speeds in the range 7–37 m/s. The coefficient of friction was exponentially reduced as a function of sliding speed reaching its minimum at 37 m/s. This behavior was provided by the mechanochemical formation of iron tungstate FeWO4 on the worn surfaces of composite samples. The lubricating effect of iron tungstate did not, however, allow for a reduction in wear. The worn surface was represented by a 3–10 μm-thickness tribological layer composed of fine WC and iron particles cemented by FeWO4. This layer provided the self-lubricating effect in high-speed (high-temperature) sliding because of its easy shear and quasi-viscous behavior. The underlying 25–65 μm of thickness layer was composed of only heat-affected WC and recrystallized iron grains.
Abstract. This work investigates the behavior of porous alumina (with the porosity ranging from 18% to 70%) and zirconia (with the porosity ranging from 10% to 60%) ceramics when subjected to deformation by compression and shearing. The analysis of stress-strain curves showed that there is a transition from a typical brittle state for relatively dense ceramics, to a pseudo-plastic one for ceramics with high porosity. The values of the effective Young's modulus, effective shear modulus and Poisson's ratio decrease with the increase of the pore space volume of ceramics, which correlates with the appearance of multiple cracking during the deformation of the high porosity ceramics.
Electron beam additive wire-feed deposition of Cu-7.5wt.%Al bronze on a stainless-steel substrate has been carried out at heat input levels 0.21, 0.255, and 0.3 kJ/mm. The microstructures formed at 0.21 kJ/mm were characterized by the presence of both zigzagged columnar and small equiaxed grains with 10% of Σ3 annealing twin grain boundaries. No equiaxed grains were found in samples obtained at 0.255 and 0.3 kJ/mm. The zigzagged columnar ones were only retained in samples obtained at 0.255 kJ/mm. The fraction of Σ3 boundaries reduced at higher heat input values to 7 and 4%, respectively. The maximum tensile strength was achieved on samples obtained with 0.21 kJ/mm as tested with a tensile axis perpendicular to the deposited wall’s height. More than 100% elongation-to-fracture was achieved when testing the samples obtained at 0.3 kJ/mm (as tested with a tensile axis coinciding with the wall’s height).
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