Knudsen effusion mass spectrometry proved to be a valuable method to study the thermodynamics of ionic liquids. The saturated vapor pressure and vaporization enthalpy of [C3MMIM(+)][Tf2N(-)] were accurately determined for the first time. MALDI is also capable of providing indirect information on hydrogen bonding.
By the methods of MALDI and mass spectroscopy with the detection of positively and negatively charged ions, it was found that the reaction of elemental sulfur and 1,3-dimethylimidazolium dimethylphosphate is accompanied by the opening of the S8 ring. 1H, 13C, 15N and 31P NMR spectroscopy showed that the interaction of S8 and 1,3-dimethylimidazolium dimethylphosphate proceeds exclusively on the oxygen atom of the dimethylphosphate anion carrying a negative charge. Kohn-Sham calculations at B3LYP/STO-3G, B3LYP/6-31G* and B3LYP/6-311G* levels of theory confirmed that the reaction of S8 with dimethylphosphate anion is possible.
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