The first order phase transitions in binary alloys were simulated basing on the Cahn–Hilliard equation for metastable states with mobility depending on the local composition. The simulation was carried out utilizing the semi-implicit Fourier spectral method for 3D fragment of a solid solution satisfying the regular solution approximation. We defined kinetics of the main characteristics of phase distribution: nucleation rate, average size, concentration of precipitates and autocorrelation function etc. Peculiarities of different stages of binary alloy decomposition (nucleation, diffusion growth and coarsening) were analyzed both for constant and variable mobility.
Here at the first time we suggested that the surface plasmon-polariton phenomenon which it is well described in metallic nanostructures could also be used for explanation of the unexpectedly strong oxidative effects of the low-intensity laser irradiation in living matters (cells, tissues, organism). We demonstrated that the narrow-band laser emitting at 1265 nm could generate significant amount of the reactive oxygen species (ROS) in both HCT116 and CHO-K1 cell cultures. Such cellular ROS effects could be explained through the generation of highly localized plasmon-polaritons on the surface of mitochondrial crista. Our experimental conditions, the low-intensity irradiation, the narrow spectrum band (<4 nm) of the laser and comparably small size bio-structures (~10 μm) were shown to be sufficient for the plasmon-polariton generation and strong laser field confinement enabling the oxidative stress observed.
In this study, we simulate nucleation in binary alloys with respect to thermal fluctuations of the alloy composition. The simulation is based on the Cahn–Hilliard–Cook equation. We have considered the influence of some fluctuation parameters (wave vector cutoff and noise amplitude) on the kinetics of nucleation and growth of minority phase precipitates. The obtained results are validated by the example of iron–chromium alloys.
The design of a fiber-optic dosimeter, which determines the radiation dose from the difference of radiation-induced attenuation (RIA) Δα measured in a P-doped silica fiber at λ = 413 and 470 nm, is presented along with its first test results under gamma-radiation (dose rates 0.00064 and 0.0066 Gy/s, maximal dose ~2Gy). The dose-dependence of Δα as well as of RIA at individual wavelengths is found to be well described by a power law, the exponent lying in the range 0.90-0.94. In contrast to RIA at individual wavelengths, Δα is found not to depend on dose rate and to decay only slightly on termination of irradiation. Therefore, using Δα for dosimetry is argued to be more promising.
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