Chain entanglement, either cohesional or topological, distinguishes polymers from other engineering materials. It impedes the movement of molecular segments and influences the polymer rheology, morphology, and mechanical properties. Although a high level of entanglement can increase the polymer toughness, excessive entanglement should be avoided because it causes a high melt viscosity making the processing difficult. This review tended to elucidate the influence of entanglement on the polymer structure, determining the material properties and processability. A wide range of methods used to fine control the degrees of chain entanglement are summarized. The methods are applicable to polymers in solutions, melts, and condensed states with advantages and limitations discussed in detail. The authors also examined the effect of the entanglement on polymer crystallization—the mechanism remains a controversial issue. This review will provide general guidance to designing and processing polymer materials with desired properties via a rational route of controlling the chain entanglement.
To increase
the maximum internal pressure that a polyethylene (PE) pipe can withstand,
a novel rotational shear system (RSS) was constructed in this study
to fabricate PE pipes with enhanced hoop strength by applying hoop
shear on the pipes using a rotational mandrel. The microstructure
and morphology with the influences of melt plasticizing temperature
on PE pipes processing under rotational shear were investigated indirectly
using small-angle X-ray scattering and wide-angle X-ray diffraction
(SAXS/WAXD) measurements. In the SAXS patterns, equatorial streaks
and meridional scattering peaks were clearly observed in all three
samples prepared at different melt plasticizing temperatures, 215,
235, and 255 °C. Their presence indicated that shish–kebab
crystals form in rotational shear. Compared to those at
the low melt temperature, the increase in the melt temperature enhanced
the amount and the dimensions of shish formed. However, the shish
also relaxed faster at the high melt temperature. This behavior was
attributed to the enhancement of the molecular chain’s athletic
ability. The hoop tensile strength and the heat resistance of the
pipes peaked at the melt plasticizing temperature of
235 °C, 75.2 MPa, 102.4 °C, up 1 MPa, 0.2 °C (compared
to the 215 °C) and 7.8 MPa, 3.2 °C (compared to the 255
°C). The axial strength increased with an increase
of melt plasticizing temperature. However, the increase of melt plasticizing
temperature worsens the inherent good tensile toughness of PE100 pipes
as the
axial elongation at break decreases.
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