Electrons bound in highly charged heavy ions such as hydrogen-like bismuth 209Bi82+ experience electromagnetic fields that are a million times stronger than in light atoms. Measuring the wavelength of light emitted and absorbed by these ions is therefore a sensitive testing ground for quantum electrodynamical (QED) effects and especially the electron–nucleus interaction under such extreme conditions. However, insufficient knowledge of the nuclear structure has prevented a rigorous test of strong-field QED. Here we present a measurement of the so-called specific difference between the hyperfine splittings in hydrogen-like and lithium-like bismuth 209Bi82+,80+ with a precision that is improved by more than an order of magnitude. Even though this quantity is believed to be largely insensitive to nuclear structure and therefore the most decisive test of QED in the strong magnetic field regime, we find a 7-σ discrepancy compared with the theoretical prediction.

We performed a laser spectroscopic determination of the 2s hyperfine splitting (HFS) of Li-like 209 Bi 80+ and repeated the measurement of the 1s HFS of H-like 209 Bi 82+ . Both ion species were subsequently stored in the Experimental Storage Ring at the GSI Helmholtzzentrum für Schwerionenforschung Darmstadt and cooled with an electron cooler at a velocity of ≈ 0.71 c. Pulsed laser excitation of the M 1 hyperfine-transition was performed in anticollinear and collinear geometry for Bi 82+ and Bi 80+ , respectively, and observed by fluorescence detection. We obtain ∆E (1s) = 5086.3(11) meV for Bi 82+ , different from the literature value, and ∆E (2s) = 797.50(18) meV for Bi 80+ . These values provide experimental evidence that a specific difference between the two splitting energies can be used to test QED calculations in the strongest static magnetic fields available in the laboratory independent of nuclear structure effects. The experimental result is in excellent agreement with the theoretical prediction and confirms the sum of the Dirac term and the relativistic interelectronic-interaction correction at a level of 0.5% confirming the importance of accounting for the Breit interaction.Quantum electrodynamics (QED) is generally considered to be the best-tested theory in physics. In recent years a number of extremely precise experimental tests have been achieved on free particles as well as on bound states in light atomic systems. For free particles, the g-factor of the electron measured with ppb-accuracy [1] constitutes the most precise test, sensitive to the highest order in α [2]. In atomic systems the QED deals with the particles bound by the Coulomb field, what makes high-precision QED calculations more complicated. The bound-state QED (BS-QED) effects in light atomic systems are expanded in parameters Zα and m e /M in addition to α, where Z is the atomic number and m e and M are the electron and nuclear masses, respectively. The parameter Zα characterizes the binding strength in the Coulomb field of the nucleus, while the mass ratio m e /M is introduced for the nuclear recoil effects. Hence, tests of BS-QED are complementary to QED tests of the properties of free particles. The investigation of H-like systems with increasing charge provides the opportunity to systematically increase the influence of the binding effect.One of the most accurate test of BS-QED on low-Z ions is the measurement of the g-factor of a single electron bound to a Si nucleus [3]. Entering the regime of highly charged heavy ions like Pb 81+ , Bi 82+ or U 91+ the electron binding energy becomes comparable to the rest-mass energy and the parameter Zα can not be employed as an expansion parameter anymore. In other words, the extremely strong electric and magnetic fields in the close surrounding of the heavy nucleus require the inclusion of the binding corrections in all orders of Zα. Hence, BS-QED in this regime requires a very different approach and new tools to calculate the corresponding corrections, usually referred to as strong-fi...

We report an improved measurement of the hyperfine splitting in hydrogen-like bismuth (209Bi82+) at the experimental storage ring ESR at GSI by laser spectroscopy on a coasting beam. Accuracy was improved by about an order of magnitude compared to the first observation in 1994. The most important improvement is an in situ high voltage measurement at the electron cooler (EC) platform with an accuracy at the 10 ppm level. Furthermore, the space charge effect of the EC current on the ion velocity was determined with two independent techniques that provided consistent results. The result of nm provides an important reference value for experiments testing bound-state quantum electrodynamics in the strong magnetic field regime by evaluating the specific difference between the splittings in the hydrogen-like and lithium-like ions.

We have performed laser cooling of Mg + ions confined in a Penning trap. The externally produced ions were captured in flight, stored and laser cooled. Laser-induced fluorescence was observed perpendicular to the cooling laser axis. Optical detection down to the single ion level together with electronic detection of the ion oscillations inside the Penning trap have been used to acquire information on the ion storage time, ion number and ion temperature. Evidence for formation of ion crystals has been observed. These investigations are an important prerequisite for sympathetic cooling of simultaneously stored highly-charged ions and precision laser spectroscopy of forbidden transitions in these.