Rapid improvement of wearable electronics stimulates the demands for the matched functional devices and energy storage devices. Meanwhile, wearable microsystem requires every parts possessing high compressibility to accommodate large-scale mechanical deformations and complex conditions. In this work, a general carbon nanotube-polydimethylsiloxane (CNT-PDMS) sponge electrode is fabricated as the elementary component of the compressible system. CNT-PDMS sponge performs high sensitivity as a piezoresistance sensor, which is capable of detecting stress repeatedly and owns great electrochemical performance as a compressible supercapacitor which maintains stably under compressive strains, respectively. Assembled with the piezoresistance sensor and the compressible supercapacitor, such highly compressible integrated system can power and modulate the low-power electronic devices reliably. More importantly, attached to the epidermal skin or clothes, it can detect human motions, ranging from speech recognition to breathing record, thus showing feasibility in real-time health monitor and human-machine interfaces.

Bending and pressure sensors are very essential for evaluating external stimuli in human motions; however, most of them are separate devices. Here, two orthogonal carbon nanotube–polyurethane sponge strips (CPSSs) are used, each of which has different resistances when bent or pressed, to fabricate a multi‐functional stretchable sensor capable of detecting omnidirectional bending and pressure independently. Due to the shape of the strip, the resistance of CPSS changes differently when bent along different directions. Based on this feature, two perpendicular CPSSs can reflect information of both bending distance and bending direction. After basic measurement data are obtained, a function set can be formulated to calculate bending distance and bending direction simultaneously. The errors of bending distance and bending angle can be controlled to less than 4%. With the help of the triboelectric effect, which only happens when the device is pressed, the sensor can differentiate bending and pressure effectively, ensuring the device works in complex situations.

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The progress of smart skin technology presents unprecedented opportunities for artificial intelligence. Resolution enhancement and energy conservation are critical to improve the perception and standby time of robots. Here, we present a self-powered analogue smart skin for detecting contact location and velocity of the object, based on a single-electrode contact electrification effect and planar electrostatic induction. Using an analogue localizing method, the resolution of this two-dimensional smart skin can be achieved at 1.9 mm with only four terminals, which notably decreases the terminal number of smart skins. The sensitivity of this smart skin is remarkable, which can even perceive the perturbation of a honey bee. Meanwhile, benefiting from the triboelectric mechanism, extra power supply is unnecessary for this smart skin. Therefore, it solves the problems of batteries and connecting wires for smart skins. With microstructured poly(dimethylsiloxane) films and silver nanowire electrodes, it can be covered on the skin with transparency, flexibility, and high sensitivity.

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The advancement of electronic skin envisions novel multifunctional human machine interfaces. Although motion sensing by detecting contact locations is popular and widely used in state-of-the-art flexible electronics, noncontact localization exerts fascinations with unique interacting experiences. This paper presents a self-powered noncontact electronic skin capable of detecting the motion of a surface electrified object across the plane parallel to that of the electronic skin based on electrostatic induction and triboelectric effects. The displacement of the object is calculated under the system of polar coordinates, with a resolution of 1.5 mm in the lengthwise direction and 0.76° in the angular direction. It can serve as a human machine interface due to its ability to sense noncontact motions. An additional self-powered feature, enabled by its physical principles, solves the problem of power supply. This electronic skin consists of trilayers of polyethyleneterephthalate-indium tin oxide-polydimethylsiloxane (PDMS) films, and microstructured PDMS as the electrified layer, which can be achieved through simplified, low cost, and scalable fabrication. Transparency, flexibility, and less number of electrodes enable such electronic skin to be easily integrated into portable electronic devices, such as laptops, smart phones, healthcare devices, etc.

A sandwich-shaped, self-charging power unit integrated with triboelectric nanogenerator and supercapacitor could be stably charged and drive an electrochromic device.