We propose and demonstrate a novel and compact optical-fiber temperature sensor with a high sensitivity and high figure of merit (FOM) based on surface plasmon resonance (SPR). The sensor is fabricated by employing a single-mode twin-core fiber (TCF), which is polished as a circular truncated cone and coated with a layer of gold film and a layer of polydimethylsiloxane (PDMS). Owing to the high refractive index sensitivity of SPR sensors and high thermo-optic coefficient of PDMS, the sensor realizes a high temperature sensitivity of -4.13 nm/°C to -2.07 nm/°C in the range from 20°C to 70°C, transcending most other types of optical-fiber temperature sensors. Owing to the fundamental mode beam transmitting in the TCF, the sensor realizes a high FOM of up to 0.034/°C, more than twice that of SPR sensors based on multimode fiber. The proposed temperature sensor is meaningful and will have potential applications in many fields, such as biomedical and biomaterial.
We propose and demonstrate a whispering gallery mode (WGM) resonance-based temperature sensor, where the microresonator is made of a DCM (2-[2-[4-(dimethylamino)phenyl] ethenyl]-6-methyl-4H-pyran-4-ylidene)-doped oil droplet (a liquid material) immersed in the water solution. The oil droplet is trapped, controlled, and located by a dual-fiber optical tweezers, which prevents the deformation of the liquid droplet. We excite the fluorescence and lasing in the oil droplet and measure the shifts of the resonance wavelength at different temperatures. The results show that the resonance wavelength redshifts when the temperature increases. The testing sensitivity is 0.377 nm/°C in the temperature range 25°C-45°C. The results of the photobleaching testing of the dye indicate that measured errors can be reduced by reducing the measured time. As far as we know, this is the first time a WGM temperature sensor with a liquid state microcavity has been proposed. Compared with the solid microresonator, the utilization of the liquid microresonator improves the thermal sensitivity and provides the possibility of sensing in liquid samples or integrating into the chemical analyzers and microfluidic systems.
Proton exchange membranes (PEMs) with both high selectivity and high permeance are of great demand in hydrogen-based applications, especially in fuel cells. Although graphene membranes have shown high selectivity of protons over other ions and molecules, the relatively low permeance of protons through perfect pristine graphene restricts its practical applications. Inspired by the nitrogen-assisted proton transport in biological systems, we introduced N-doping to increase the proton permeance and proposed a type of N-doped graphene membranes (NGMs) for proton exchange, which have both high proton permeance and high selectivity. Compared to the state-of-the-art commercial PEMs, the NGMs show significant increases in both areal proton conductivity (2−3 orders of magnitude) and selectivity of proton to methanol (1−2 orders of magnitude). The work realized the controllable tuning of proton permeance of the graphene membrane with N-doping and developed a new type of graphene-based PEMs with high performance for practical applications.
Curvature measurement plays an important role in many fields. Aiming to overcome shortcomings of the existing optical fiber curvature sensors, such as complicated structure and difficulty in eliminating temperature noise, we proposed and demonstrated a simple optical fiber curvature sensor based on surface plasmon resonance. By etching cladding of the step-index multimode fiber and plating gold film on the bare core, the typical Kretschmann configuration is implemented on fiber, which is used as the bending-sensitive region. With increases in the curvature of the optical fiber, the resonance wavelength of the SPR (Surface Plasmon Resonance) dip linear red-shifts while the transmittance decreases linearly. In the curvature range between 0 and 9.17 m−1, the wavelength sensitivity reached 1.50 nm/m−1 and the intensity sensitivity reached −3.66%/m−1. In addition, with increases in the ambient temperature, the resonance wavelength of the SPR dips linearly blueshifts while the transmittance increases linearly. In the temperature range between 20 and 60 °C, the wavelength sensitivity is −0.255 nm/°C and the intensity sensitivity is 0.099%/°C. The sensing matrix is built up by combining the aforementioned four sensitivities. By means of the dual modulation method, the cross-interference caused by temperature change is eliminated. Additionally, simultaneous measurement of curvature and temperature is realized.
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