In recent decades, the removal of hazardous chemicals that have entered wastewater and groundwater as a result of industrial and consumer activities has become an issue of concern. Specifically, removing arsenic (III) from groundwater is critical and equally crucial in the use of low-cost, efficient adsorbent materials. One purpose of this study was to develop a low-cost hydroxyapatite adsorbent (Ca5(PO4)3OH) by reacting the Ca component of calcined dolomite with phosphorus, and another was to apply the developed adsorbent to remove arsenic (III) from well water in developing countries. In this study, phosphorus adsorption was performed on thermally calcined dolomite, and the adsorption isotherm of the phosphorus study was investigated on selected calcined dolomite. The maximum amount of phosphorus on the selected calcined dolomite was 194.03 mg-P/g, and the Langmuir isotherm model was fitted. Arsenic (III) adsorption was investigated in a wide pH range (pH 2~12) using the new adsorbent. The amount of arsenic (III) adsorbed was 4.3 mg/g. The new absorbent could be effective in removing arsenic (III) and become an affordable material.
There are numerous methods and additives available to improve the durability and quality of road bitumen. A coal tar obtained by coal coking was distilled in a laboratory into fractions of initial boiling point IBP-180˚C (gasoline-like fuel), 180˚C -360˚C (diesel-like fuel), and >360˚C (residue or coal tar pitch). The coal tar pitch was added into road bitumen by up to 1 -5 wt% and investigated the alteration of physical and chemical properties. The physico-mechanical properties of coal tar pitch and bitumen blends, as well as the chemical group composition, were determined using standard techniques (MNS) and the SARA method, respectively. Results of 3% coal tar pitch addition into bitumen enhanced ductility by 12.4% and softening point by 1.6˚C. We found that blending with bitumen coal tar pitch as a modifier could improve bitumen properties.
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