With the rapid development of energy storage devices, aqueous battery with noncombustion properties and instinct safe features has received great attentions and Zn anode is investigated intensively due to its high theoretical capacity (820 mAh g−1), and low negative potential (−0.762 V vs SHE). However, the unavoidable gas evolution hinders the cyclability and the application in the commercial field. Herein, the atomic layer deposition of TiO2 coating is first demonstrated as the protection layer of metallic zinc anode. The corrosion of zinc plate is significantly suppressed, leading to less gas evolution and Zn(OH)2 byproduct formation. The reduced gas generation on the outer surface of the zinc plate will maintain the effective contact area between the electrolyte and anode and leads to an improved coulombic efficiency. In this way, the Zn anode with 100 ALD cycles TiO2 protection shows reduced overpotential (72.5 mV) at 1 mA cm−2 for Zn–Zn symmetrical battery and additionally, the protection of TiO2 extended the Zn–MnO2 battery cycling performance up to 1000 cycles with the capacity retention of 85% at current density of 3 mA cm−2. The novel design of atomic layer deposition protected metal zinc anode brings in new opportunities to the realization of the ultrasafe aqueous zinc metal batteries.
Aqueous rechargeable zinc ion batteries are considered a promising candidate for large‐scale energy storage owing to their low cost and high safety nature. A composite material comprised of H2V3O8 nanowires (NWs) wrapped by graphene sheets and used as the cathode material for aqueous rechargeable zinc ion batteries is developed. Owing to the synergistic merits of desirable structural features of H2V3O8 NWs and high conductivity of the graphene network, the H2V3O8 NW/graphene composite exhibits superior zinc ion storage performance including high capacity of 394 mA h g−1 at 1/3 C, high rate capability of 270 mA h g−1 at 20 C and excellent cycling stability of up to 2000 cycles with a capacity retention of 87%. The battery offers a high energy density of 168 W h kg−1 at 1/3 C and a high power density of 2215 W kg−1 at 20 C (calculated based on the total weight of H2V3O8 NW/graphene composite and the theoretically required amount of Zn). Systematic structural and elemental characterization confirm the reversible Zn2+ and water cointercalation electrochemical reaction mechanism. This work brings a new prospect of designing high‐performance aqueous rechargeable zinc ion batteries for grid‐scale energy storage.
Piezoelectric biomaterials are intrinsically suitable for coupling mechanical and electrical energy in biological systems to achieve in vivo real-time sensing, actuation, and electricity generation. However, the inability to synthesize and align the piezoelectric phase at a large scale remains a roadblock toward practical applications. We present a wafer-scale approach to creating piezoelectric biomaterial thin films based on γ-glycine crystals. The thin film has a sandwich structure, where a crystalline glycine layer self-assembles and automatically aligns between two polyvinyl alcohol (PVA) thin films. The heterostructured glycine-PVA films exhibit piezoelectric coefficients of 5.3 picocoulombs per newton or 157.5 × 10−3 volt meters per newton and nearly an order of magnitude enhancement of the mechanical flexibility compared with pure glycine crystals. With its natural compatibility and degradability in physiological environments, glycine-PVA films may enable the development of transient implantable electromechanical devices.
The manifestation of acute kidney injury (AKI) is associated with poor patient outcomes, with treatment options limited to hydration or renal replacement therapies. The onset of AKI is often associated with a surfeit of reactive oxygen species. Here, it is shown that selenium‐doped carbon quantum dots (SeCQDs) have broad‐spectrum antioxidant properties and prominent renal accumulation in both healthy and AKI mice. Due to these properties, SeCQDs treat or prevent two clinically relevant cases of AKI induced in murine models by either rhabdomyolysis or cisplatin using only 1 or 50 µg per mouse, respectively. The attenuation of AKI in both models is confirmed by blood serum measurements, kidney tissue staining, and relevant biomarkers. The therapeutic efficacy of SeCQDs exceeds amifostine, a drug approved by the Food and Drug Administration that also acts by scavenging free radicals. The findings indicate that SeCQDs show great potential as a treatment option for AKI and possibly other ROS‐related diseases.
Creating two dimensional (2D) geometry from non-layered catalytic materials may significantly advance electrocatalysts design. 2D morpohology of three dimensional lattices (2D non-layered materials) offer large structure distortions, massive surface dangling...
A fully distributed optical fiber vibration sensor is demonstrated based on spectrum analysis of Polarization-OTDR system. Without performing any data averaging, vibration disturbances up to 5 kHz is successfully demonstrated in a 1km fiber link with 10m spatial resolution. The FFT is performed at each spatial resolution; the relation of the disturbance at each frequency component versus location allows detection of multiple events simultaneously with different and the same frequency components.
Resistance exercise is beneficial in terms of reducing pain, alleviating stiffness, and improving physical function in patients with knee osteoarthritis.
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