A highly chemo‐ and regioselective intermolecular 1,2‐aryl‐aminoalkylation of alkenes by photoredox/nickel dual catalysis is described here. This three‐component conjunctive cross‐coupling is highlighted by its first application of primary alkyl radicals, which were not compatible in previous reports. The readily prepared α‐silyl amines could be transferred to α‐amino radicals by photo‐induced single electron transfer step. The radical addition/cross‐coupling cascade reaction proceeds under mild, base‐free and redox‐neutral conditions with good functional group tolerance, and importantly, provides an efficient and concise method for the synthesis of structurally valuable α‐aryl substituted γ‐amino acid derivatives motifs.

The electromagnetically induced transparency (EIT) effect realized in a metasurface is potential for slow light applications for its extreme dispersion variation in the transparency window. Herein, we propose an all-dielectric metasurface to generate a double resonance-trapped quasi bound states in the continuum (BICs) in the form of EIT or Fano resonance through selectively exciting the guiding modes with the grating. The group delay of the EIT is effectively improved up to 2113 ps attributing to the ultrahigh Q-factor resonance carried by the resonance-trapped quasi-BIC. The coupled harmonic oscillator model and a full multipole decomposition are utilized to analyze the physical mechanism of EIT-based quasi-BIC. In addition, the BIC based on Fano and EIT resonance can simultaneously exist at different wavelengths. These findings provide a new feasible platform for slow light devices in the near-infrared region.

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A visible light‐induced photocyanation of tertiary amines by a stable, less‐toxic and user‐friendly CN reagent cyanobenziodoxolone (CBX) was developed. This cyanation process does not require any photocatalyst, oxidant, base or additives, representing a set of extremely mild and succinct reaction conditions and a broad substrate scope. In addition to the frequently used N‐aryl amine derivatives, more challenging tertiary aliphatic amines (modified by a α‐silyl substituent) can also be photocyanated smoothly. Mechanistic studies reveal that the cyanation reaction is enabled by an electron donor–acceptor (EDA) complex formed by the interaction between the amine and the cyanobenziodoxolone reagent.

A highly chemo‐ and regioselective intermolecular 1,2‐aryl‐aminoalkylation of alkenes by photoredox/nickel dual catalysis is described here. This three‐component conjunctive cross‐coupling is highlighted by its first application of primary alkyl radicals, which were not compatible in previous reports. The readily prepared α‐silyl amines could be transferred to α‐amino radicals by photo‐induced single electron transfer step. The radical addition/cross‐coupling cascade reaction proceeds under mild, base‐free and redox‐neutral conditions with good functional group tolerance, and importantly, provides an efficient and concise method for the synthesis of structurally valuable α‐aryl substituted γ‐amino acid derivatives motifs.

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