Natural zeolite, as an abundant aluminosilicate mineral with a hierarchically porous structure, has a strong affinity to ammonium in solutions. Adsorption mechanism of high-concentration ammonium (1000~4000 mg-N/L) in an aqueous solution without pH adjustment onto Chinese natural zeolite with the dosage of 5 g/L was revealed by the strategy of experimental optimization integrated with Molecular Dynamics (MD) simulation, and found the maximum ammonium adsorption capacity was 26.94 mg/g. The adsorption kinetics and isotherm analysis showed that this adsorption process fitted better with descriptions of the pseudo-second-order kinetics and Freundlich model. The theoretical calculations and infrared-spectrum characterization results verified the existence of hydrogen bonds and chemisorption. Therefore, the adsorption mechanism by natural zeolites of high-concentration NH4+ is defined as a process under the joint influence of multiple effects, which is mainly promoted by the synergy of the ion exchange process, electrostatic attraction, and chemisorption. Meanwhile, the hydrogen bond also plays an auxiliary role in this efficient adsorption. This study presents important theoretical significance for enriching the mechanism of zeolites adsorbing NH4+ from water, and provides reference and theoretical guidance for further exploring the potential application of natural zeolites.
This study systematically analysed the distribution characteristics, sources and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in Kuye River sediments in an energy and chemical industry base in northern Shaanxi, China. The results revealed the concentrations of 16 PAHs in the sediment ranged from 1090.04 to 32175.68 ng∙g− 1 dw, with the highest proportion of 4-rings PAHs; PMF revealed the main sources of PAHs were the incomplete combustion of fossil fuel, biomass combustion and traffic emissions. The total toxic equivalent concentration of BaP, risk quotient and life time carcinogenic risk of PAHs suggested the moderate to high contamination of PAHs. The higher ILCR indicated the ingestion of PAHs was the main way to impact public health, and children should be more susceptible to PAHs. This study could provide theoretical support for pollution prevention measures and ecological restoration strategies for rivers in energy and chemical areas.
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