Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties.
In previous research, sucrose and citric acid were used to synthesize an eco-friendlyplywood adhesive. Herein, further research was performed to determine the optimal hot-pressingconditions and curing behavior of a sucrose-citric acid (SC) adhesive. The results of dry and wetshear strength measurements showed that the optimal hot-pressing temperature, hot-pressing time,and spread rate of plywood samples bonded by the SC adhesive were 190 °C, 7 min, and 140 g/m2,respectively. When plywood was bonded at the optimal hot-pressing conditions, the wet shearstrength met the requirements of the China National Standard GB/T 9846-2015. Thermal analysisshowed that the thermal degradation and endothermic reaction temperatures of the SC 25/75adhesive were lower than either sucrose or citric acid individually. In addition, the insoluble massproportion increased with the heating temperature and time. The Pyrolysis Gas Chromatographyand Mass Spectrometr (Py-GC/MS) analysis confirmed that the SC adhesive was cured by thereaction between furan compounds, saccharide, and citric acid, and the resulting polymer appearedto be joined by ether linkages.
The development of eco-friendly adhesives for wood composite products has been a major topic in the field of wood science and product engineering. Although the research on tannin-based and soybean protein-based adhesives has already reached, or at least nears, industrial implementation, we also face a variety of remaining challenges with regards to the push for sustainable adhesives. First, petroleum-derived substances remain a pre-requisite for utilization of said adhesive systems, and also the viscosity of these novel adhesives continues to limit its ability to serve as a drop-in substitute. Within this study, we focus upon the development of an eco-friendly plywood adhesive that does not require any addition of petroleum derived reagents, and the resultant liquid adhesive has both high solid contents as well as a manageably low viscosity at processing temperatures. Specifically, a system based on sucrose and ammonium dihydrogen phosphate (ADP) was synthesized into an adhesive with ~80% solid content and with viscosities ranging from 480–1270 mPa·s. The bonding performance of all adhesive-bound veneer specimens satisfied GB/T 9846-2015 standard at 170 °C hot pressing temperature. To better explain the system’s efficiency, in-depth chemical analysis was performed in an effort to understand the chemical makeup of the cured adhesives as well as the components over the time course of curing. Several new structures involving the fixation of nitrogen speak to a novel adhesive molecular network. This research provides a possibility of synthesizing an eco-friendly wood adhesive with a high solid content and a low viscosity by renewable materials, and this novel adhesive system has the potential to be widely utilized in the wood industry.
The development of eco-friendly adhesives is a major research direction in the wood-based material industry. Previous research has already demonstrated the mixture of sucrose and citric acid could be utilized as an adhesive for the manufacture of particleboard. Herein, based on the chemical characteristics of sucrose, a synthesized sucrose-citric acid (SC) adhesive was prepared, featuring suitable viscosity and high solid content. The investigation of synthesis conditions on the bond performance showed that the optimal mass proportion between sucrose and citric acid was 25/75, the synthesis temperature was 100 °C, and the synthesis time was 2 h. The wet shear strength of the plywood bonded with SC adhesive, which was synthesized at optimal conditions and satisfied the China National Standard GB/T 9846-2015. The synthesis mechanism was studied by both 13C NMR analysis and HPLC, and the chemical composition manifesting caramelization reaction occurred during the synthesis process. The results of ATR FT-IR indicated the formation of a furan ring, carbonyl, and ether groups in the cured insoluble matter of the SC adhesive, which indicated dehydration condensation as the reaction mechanism between sucrose and citric acid.
Sucrose is one of the most abundantly available renewable chemicals in the world, and it is expected to be utilized as a raw material for wood-based material products. Herein, a novel adhesion system that was based on sucrose and ammonium dihydrogen phosphate (ADP) was synthesized into an adhesive with 80% solid content, and this eco-friendly was utilized on the fabrication of plywood. The effects of the synthesis conditions on the plywood bond performance and synthesis mechanism were investigated. The optimal synthesis conditions were as follows: the mass proportion between sucrose and ADP was 90/10, the synthesis temperature was 90 °C, and the synthesis time was 3 h. The bonding performance of the plywood that was bonded by optimal SADP adhesive satisfied the GB/T 9846-2015 standard. The chemical analysis was performance tested by using High-Performance Liquid Chromatography (HPLC), Attenuated Total Reflection-Fourier Transform Infrared Spectra (ATR-FTIR), and Pyrolysis Gas Chromatography and Mass Spectrometry (Py-GC/MS) to understand the chemical transformation during the synthesis process. The chemical analysis results confirmed that the hydrolysis and conversation reaction of sucrose occurred in the synthesized SADP adhesive, and ADP promoted the pyrolysis efficiency of sucrose.
In a previous study by the authors, particleboard was manufactured using a new natural adhesive composed of tannin and sucrose. The optimal ratio between tannin and sucrose was 25/75, and the suitable resin content was 30 to 40 wt%. In this study, the effects of hot pressing temperature and hot pressing time on board properties were investigated. The optimal values for the hot pressing temperature and hot pressing time were found to be 220 °C and 10 min, respectively. When the particleboard was made under these optimum conditions, the physical properties of the particleboard bonded with tannin and sucrose met the requirement of the JIS A 5908 type 18 standard (2003). Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), insoluble matter, and Fourier transform infrared spectroscopy (FT-IR) tests were carried out. The results of TGA and DSC measurements showed that the weight loss and endothermic reaction of the adhesive composed of tannin and sucrose at a ratio of 25/75 occurred at 204 and 215 °C, respectively. When the adhesive was heated at 220 °C for longer than 10 min, the level of insoluble matter was higher than 70 wt%. FT-IR analysis showed the existence of a furan ring, a carbonyl group, and dimethylene ether bridges in the cured adhesives before and after the boiling treatment. When the heating time was longer than 10 min, no further change of chemical structure was observed.
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