The rapid development of integrated electronics and the boom in miniaturized and portable devices have increased the demand for miniaturized and on-chip energy storage units. Currently thin-film batteries or microsized batteries are commercially available for miniaturized devices. However, they still suffer from several limitations, such as short lifetime, low power density, and complex architecture, which limit their integration. Supercapacitors can surmount all these limitations. Particularly for micro-supercapacitors with planar architectures, due to their unique design of the in-plane electrode finger arrays, they possess the merits of easy fabrication and integration into on-chip miniaturized electronics. Here, the focus is on the different strategies to design electrode finger arrays and the material engineering of in-plane micro-supercapacitors. It is expected that the advances in micro-supercapacitors with in-plane architectures will offer new opportunities for the miniaturization and integration of energy-storage units for portable devices and on-chip electronics.
The binary skutterudite CoSb3 is a narrow bandgap semiconductor thermoelectric (TE) material with a relatively flat band structure and excellent electrical performance. However, thermal conductivity is very high because of the covalent bond between Co and Sb, resulting in a very low ZT value. Therefore, researchers have been trying to reduce its thermal conductivity by the different optimization methods. In addition, the synergistic optimization of the electrical and thermal transport parameters is also a key to improve the ZT value of CoSb3 material because the electrical and thermal transport parameters of TE materials are closely related to each other by the band structure and scattering mechanism. This review summarizes the main research progress in recent years to reduce the thermal conductivity of CoSb3-based materials at atomic-molecular scale and nano-mesoscopic scale. We also provide a simple summary of achievements made in recent studies on the non-equilibrium preparation technologies of CoSb3-based materials and synergistic optimization of the electrical and thermal transport parameters. In addition, the research progress of CoSb3-based TE devices in recent years is also briefly discussed.
Flexible devices play an important role in various fields such as electronics, industry, healthcare, military, space exploration, and so on. Traditional materials used for flexible devices include silicon, inorganic oxides,...
How to prevent the agglomeration of nanoparticles in
nanocomposites
remains a key challenge. Using nanometer suspension as a doping agent
provides an effective approach to solve this challenge. A new technique
that consists of chemical coprecipitation, ball milling and sedimentation
separation metheds was developed for preparing hard magnetic M-type
BaFe12O19 nanometer suspension. The single-phase
BaFe12O19 nanoparticles dispersed uniformly
in alcohol have been prepared by this new technique. Magnetic nanocomposite
thermoelectric materials with a homogeneous dispersion of BaFe12O19 nanoparticles were prepared through a combination
process of an ultrasonic mixing of BaFe12O19 nanometer suspension and In-filled CoSb3 thermoelectric
matrix material and spark plasma sintering. The microstructure analysis
of magnetic nanocomposite thermoelectric materials confirmed that
using the nanometer suspension as a doping agent is an effective way
to solve the agglomeration phenomenon of nanoparticles in nanocomposites.
In addition, the decline of thermoelectric performance in the high-temperature
intrinsic excitation region of In-filled CoSb3 can be effectively
suppressed by the magnetic phase transition of BaFe12O19 nanoparticles dried by nanometer suspension from ferromagnetism
to paramagnetism. It is also confirmed that using the BaFe12O19 nanometer suspension as a thermoelectric performance
enhancer is an effective way to solve the challenging problem of performance
deterioration of thermoelectric materials at high temperature.
Indoor formaldehyde from substandard
furniture and decorative materials
seriously endangers human health. How to remove effectively indoor
formaldehyde with low concentration at room temperature is a challenging
problem. Using a MnO2/AlOOH composite by the MnO2 modification as a catalyst provides an effective approach to solve
this challenge. Here, a new type of MnO2/AlOOH composite
catalyst with high ability to remove indoor low-concentration formaldehyde
was prepared by redox reaction at room temperature. A MnO2/AlOOH composite with a homogeneous dispersion of MnO2 has high specific surface area and a large amount of surface hydroxyl
(−OH) which plays a major role in the adsorption of formaldehyde.
A partially crystalline structure was observed in the composite, which
contains multivalent Mn ions and a large number of vacancy defects.
The surface −OH of composite shows strong oxidation activity
through the charge exchange of multivalent Mn ions and vacancy defects.
The composite has a higher ability to remove indoor low-concentration
formaldehyde compared to the birnessite MnO2 at room temperature.
This study proposes a new idea for the improvement of catalytic performance
in the structure and composition of the catalyst.
How
to realize the synergistic optimization of electrical–thermal–mechanical
properties of thermoelectric materials is a key challenge. Using the
Bi0.5Sb1.5Te3 nanoparticle as a mixed
agent provides an effective way to address this challenge. Here, Bi0.5Sb1.5Te3/In0.25Co4Sb12 nanocomposites with different contents of Bi0.5Sb1.5Te3 nanoparticles were successfully
prepared by ultrasonic dispersion combined with spark plasma sintering.
Phase and microstructure characterization presented that Te nanoparticles
were precipitated from Bi0.5Sb1.5Te3 during the SPS sintering process. Transport measurement results
showed that the electrical conductivity was increased due to the increased
carrier concentration induced by the charge transfer between Te nanoparticles
and the matrix. The Seebeck coefficient was also increased due to
the selected electron scattering and increased scattering factor.
The lattice thermal conductivity was dramatically suppressed because
of the enhanced phonon scattering induced by the Bi0.5Sb1.5Te3 nanoparticles and in situ-precipitated Te
nanoparticles and increased dislocations. As a result, a higher average ZT value of 1 was obtained in the range of 300–700
K by the decoupling of the electrical and thermal transport properties
for the nanocomposite with 0.1 wt % of Bi0.5Sb1.5Te3 nanometer suspension. Furthermore, the flexural strength,
fracture toughness, and hardness of the nanocomposites were also improved
significantly. This work demonstrates that using the Bi0.5Sb1.5Te3 nanoparticle as a mixed agent can
realize the synergistic optimization of electrical–thermal–mechanical
properties of the In-filled CoSb3 thermoelectric material.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.