We demonstrate a new approach to utilize copper(I) iodide coordination complexes as emissive layers in organic light-emitting diodes (OLEDs), by in situ codeposition of copper(I) iodide and 3,5-bis(carbazol-9-yl)pyridine (mCPy). With a simple three-layer device structure, pure green electroluminescence at 530 nm from a copper(I) complex was observed. Maximum luminance and external quantum efficiency (EQE) of 9700 cd/m2 and 4.4% have been achieved, respectively. The luminescent species has been identified as [CuI(mCPy)2]2 based on photophysical studies of model complexes and X-ray absorption spectroscopy (XAS).
White organic light‐emitting diodes (WOLEDs) are currently under intensive research and development worldwide as a new generation light source to replace problematic incandescent bulbs and fluorescent tubes. One of the major challenges facing WOLEDs has been to achieve high energy efficiency and high color rendering index simultaneously to make the technology competitive against other alternative technologies such as inorganic LEDs. Here, an all‐phosphor, four‐color WOLEDs is presented, employing a novel device design principle utilizing molecular energy transfer or, specifically, triplet exciton conversion within common organic layers in a cascaded emissive zone configuration to achieve exceptional performance: an 24.5% external quantum efficiency (EQE) at 1000 cd/m2 with a color rendering index (CRI) of 81, and an EQE at 5000 cd/m2 of 20.4% with a CRI of 85, using standard phosphors. The EQEs achieved are the highest reported to date among WOLEDs of single or multiple emitters possessing such high CRI, which represents a significant step towards the realization of WOLEDs in solid‐state lighting.
Active matrix organic light-emitting diode (AMOLED) display holds great potential for the next generation visual technologies due to its high light efficiency, flexibility, lightweight, and low-temperature processing. However, suitable thin-film transistors (TFTs) are required to realize the advantages of AMOLED. Preseparated, semiconducting enriched carbon nanotubes are excellent candidates for this purpose because of their excellent mobility, high percentage of semiconducting nanotubes, and room-temperature processing compatibility. Here we report, for the first time, the demonstration of AMOLED displays driven by separated nanotube thin-film transistors (SN-TFTs) including key technology components, such as large-scale high-yield fabrication of devices with superior performance, carbon nanotube film density optimization, bilayer gate dielectric for improved substrate adhesion to the deposited nanotube film, and the demonstration of monolithically integrated AMOLED display elements with 500 pixels driven by 1000 SN-TFTs. Our approach can serve as the critical foundation for future nanotube-based thin-film display electronics.
Figure 5. Performance of LED devices of Q-2D perovskite. a) Cross-section scanning electron microscopy (SEM) image of the device; scale bar: 500 nm. b,c) Current-efficiency-voltage (CE-V) curves of the Q-2D perovskite LED devices with different alkali-metal ions incorporated (b) and different amounts of KBr incorporated (c). d) J-V-L-EQE curves of the champion device with 0.5KBr added. e) Histogram of maximum EQE measured from 50 devices with 0.5KBr added. f) Stability of the perovskite LED measured at a constant current density of 0.25 mA cm -2 , with an initial luminance around 140 cd m -2 .
Organic light-emitting diodes (OLEDs) based on red and green phosphorescent iridium complexes are successfully commercialized in displays and solid-state lighting. However, blue ones still remain a challenge on account of their relatively dissatisfactory Commission International de L'Eclairage (CIE) coordinates and low efficiency. After analyzing the reported blue iridium complexes in the literature, a new deep-blue-emitting iridium complex with improved photoluminescence quantum yield is designed and synthesized. By rational screening host materials showing high triplet energy level in neat film as well as the OLED architecture to balance electron and hole recombination, highly efficient deep-blue-emission OLEDs with a CIE at (0.15, 0.11) and maximum external quantum efficiency (EQE) up to 22.5% are demonstrated. Based on the transition dipole moment vector measurement with a variable-angle spectroscopic ellipsometry method, the ultrahigh EQE is assigned to a preferred horizontal dipole orientation of the iridium complex in doped film, which is beneficial for light extraction from the OLEDs.
1801256 (2 of 49) www.advopticalmat.de 1801256 (4 of 49) www.advopticalmat.de the magnetic moments and heavy atom effect of lanthanide could facilitate intersystem crossing (ISC) process of the ligand and promote ligand-based phosphorescence. Scheme 3. The complexes Tb-12-Tb-25. Scheme 4. The complexes Tb-26 and Tb-27. www.advancedsciencenews.com
Phosphorescent
copper(I) complexes show great promise as emitters in organic light-emitting
diodes (OLEDs). However, most copper(I) complexes are neither soluble
nor stable toward sublimation and, hence, not amenable to the typical
methods to fabricate OLEDs. In this work, a compound 3-(carbazol-9-yl)-5-((3-carbazol-9-yl)phenyl)pyridine
(CPPyC) was designed as both a good ligand and host matrix. Codeposition
of CPPyC and copper iodide (CuI) gives luminescent films with photoluminescent
quantum yields (PLQY) as high as 100%. A dimeric copper(I) complex
Cu2I2(CPPyC)4 is formed in the thin
film, characterized by X-ray absorption spectroscopy. A series of
simple, highly efficient green-emitting OLEDs were demonstrated by
using the codeposited film as an emissive layer. A device comprised
of only CPPyC and CuI gave an external quantum efficiency (EQE) of
12.6% (42.3 cd/A) at 100 cd/m2, while a device with tailored
hole and electron transporting layers gave an efficiency of 15.7%
(51.6 cd/A) at the same brightness.
Divalent europium 5d-4f transition has aroused great attention in many fields, in a way of doping Eu2+ ions into inorganic solids. However, molecular Eu2+ complexes with 5d-4f transition are thought to be too air-unstable to explore their applications. In this work, we synthesized four Eu2+-containing azacryptates EuX2-Nn (X = Br, I, n = 4, 8) and systematically studied the photophysical properties in crystalline samples and solutions. Intriguingly, the EuX2-N8 complexes exhibit near-unity photoluminescence quantum yield, good air-/thermal-stability and mechanochromic property (X = I). Furthermore, we proved the application of Eu2+ complexes in organic light-emitting diodes (OLEDs) with high efficiency and luminance. The optimized device employing EuI2-N8 as emitter has the best performance as the maximum luminance, current efficiency, and external quantum efficiency up to 25470 cd m−2, 62.4 cd A−1, and 17.7%, respectively. Our work deepens the understanding of structure-property relationship in molecular Eu2+ complexes and could inspire further research on application in OLEDs.
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