Cellulose nanocrystals (CNCs) are a kind of sustainable nanoparticle from biomass, which are widely used as reinforcing filler and assembly building block for high‐performance composites and function materials including biomaterial, optics, and so forth. Here, their unique advantages in material applications were reviewed based on their rod‐like morphology, crystalline structure, dimension‐related effects, and multi‐level order structure. Then, we focused on the molecular engineering of CNCs, including the structure and physicochemical properties of their surface, along with surface modification methods and steric effects. We further discussed the performance‐improvement and functionalization methods based on multi‐component complex systems, together with the effects of surface molecular engineering on the performance and functions. Meanwhile, methods of optimizing orientation in uniaxial arrays were discussed along with those of enhancing photoluminescence efficiency via surface chemical modification and substance coordination. In the end, we prospected the design, development, and construction methods of new CNCs materials.
BACKGROUND: The application of chemical pesticides in control of plant bacterial disease may cause potential environmental pollution. Herein, based on the resistance-inducing ability and the special rod-like structure with high aspect ratio of bioderived chitin nanocrystals (ChNC), a new Cu composite rod-like nanoparticle was fabricated (ChNC@Cu). The antibacterial activity of the composite nanoparticle was systematically studied, and its safety was evaluated.RESULTS: TEM, FTIR, ICP and other characterization methods proved that ChNC@Cu is a nano rod-like structure, with a Cu 2+ loading capacity of 2.63%. In vitro experiments showed that the inhibition rate of ChNC@Cu to P. syringae pv. tabaci was more than 95% when the copper content was 41.6 ∼g mL −1 . In vivo experiments showed that ChNC@Cu had a good protective effect on P. syringae pv. tabaci of tobacco. In addition, ChNC@Cu exhibited stronger antibacterial activity than Thiodiazole copper (TC) at the same copper content. The study on the antibacterial mechanism of ChNC@Cu proved that ChNC@Cu caused bacterial death by destroying the bacterial cell membrane structure and damaging the DNA bacteria. And ChNC@Cu is highly safe for plants and can promote seed germination and plant growth.CONCLUSION: The special rod-like structure of ChNC can enrich Cu 2+ to form ChNC@Cu. ChNC@Cu has a good protective effect on bacterial infection of tobacco, and achieves a great antibacterial activity at low Cu 2+ concentration, which indicated that ChNC@Cu has induced resistance and antibacterial effect. As a novel green nanofungicide, ChNC@Cu has high potential application value in control of agricultural bacterial diseases.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.