The demanding all-in-one electrocatalyst system for oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in zinc-air batteries or water splitting requires elaborate material manufacturing, which is usually complicated and time-consuming. Efficient interface engineering between MXene and highly active electrocatalytic species (CoS 2 ) is, herein, achieved by an in situ hydrothermal growth and facile sulfurization process. The CoS 2 @MXene electrocatalyst is composed by one-dimensional CoS 2 nanowires and two-dimensional MXene nanosheets, which lead to a hierarchical structure (large specific surface area and abundant active sites), a spatial electron redistribution (high intrinsic activity), and high anchoring strength (superior performance stability). Therefore, the electrocatalyst achieves enhanced catalytic activity and longtime stability for ORR (a half-wave potential of 0.80 V), OER (an overpotential of 270 mV at 10 mA cm −2 , i.e., η 10 = 270 mV) and HER (η 10 = 175 mV). Furthermore, the asymmetry water splitting system based on the CoS 2 @MXene composites delivers a low overall voltage of 1.63 V at 10 mA cm −2 . The solidstate zinc-air batteries using CoS 2 @MXene as the air cathode display a small charge-discharge voltage gap (0.53 V at 1 mA cm −2 ) and superior stability (60 circles and 20-h continuous test). The energy interconversion between the chemical energy and electricity can be achieved by a self-powered system via integrating the water splitting system and quasisolid-state zinc-air batteries. Supported by in situ Raman analyses, the formation of cobalt oxyhydroxide species provides the active sites for water oxidation. This study paves a promising avenue for the design and application of multifunctional nanocatalysts.
A method is proposed to suppress sidelobe level for near-field beamforming in ultrasound array imaging. An optimization problem is established, and the second-order cone algorithm is used to solve the problem to obtain the weight vector based on the near-field response vector of a transducer array. The weight vector calculation results show that the proposed method can be used to suppress the sidelobe level of the near-field beam pattern of a transducer array. Ultrasound images following the application of weight vector to the array of a wire phantom are obtained by simulation with the Field II program, and the images of a wire phantom and anechoic sphere phantom are obtained experimentally with a 64-element 26 MHz linear phased array. The experimental and simulation results agree well and show that the proposed method can achieve a much lower sidelobe level than the conventional delay and sum beamforming method. The wire phantom image is demonstrated to focus much better and the contrast of the anechoic sphere phantom image improved by applying the proposed beamforming method.
This paper presents a detailed study of the high-order superdirectivity of circular sensor arrays, which is aimed at completing the authors' recently proposed analytical superdirectivity model. From the limit expression of the maximum directivity factor, it is shown that the circular arrays possess good potential for directivity improvement. It is found that the sensitivity function used as a robustness measurement can also be accurately decomposed into a series of closed-form sensitivity functions of eigenbeams, similar to the optimal beampattern and its corresponding directivity factor. Moreover, the performance of eigenbeams can be regarded as an indicator of error sensitivity, and the robustness constraint parameters can be estimated easily. Two specific approaches are proposed for obtaining robust superdirectivity on the basis of robustness analyses, and their performance is demonstrated experimentally.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.