A simple and effective strategy on producing solution-processable materials with highly efficient and persistent room-temperature-phosphorescence (RTP) is presented here.
Herein, new types of zero‐dimensional (0D) perovskites (PA6InCl9 and PA4InCl7) with blue room‐temperature phosphorescence (RTP) were obtained from InCl3 and aniline hydrochloride. These are highly sensitive to external light and force stimuli. The RTP quantum yield of PA6InCl9 can be enhanced from 25.2 % to 42.8 % upon illumination. Under mechanical force, PA4InCl7 exhibits a phase transform to PA6InCl9, thus boosting ultralong RTP with a lifetime up to 1.2 s. Furthermore, white and orange pure RTP with a quantum yield close to 100 % can be realized when Sb3+ was introduced into PA6InCl9. The white pure phosphorescence with a color‐rendering index (CRI) close to 90 consists of blue RTP of PA6InCl9 and orange RTP of Sb3+. Thus, this work not only overcomes long‐standing problems of low quantum yield and short lifetime of blue RTP, but also obtains high‐efficiency white RTP. It provides a feasible method to realize near‐unity quantum efficiency and has great application potential in the fields of optical devices and smart materials.
Ultralong and colorful clusterization-triggered phosphorescence (CTP) has been realized by changing polymerization conditions of polyacrylamides (PAMs). These materials have huge potential in the application of sensing, anti-counterfeiting and LEDs.
The rich molecular design of electron donor (D)–acceptor (A) polymers offers many valuable clues to obtain high‐efficiency hole‐transporting materials (HTMs) for use in perovskite solar cells (PVSCs). The fused aromatic or heteroaromatic units can increase the conjugation of the polymer backbone to facilitate electron delocalization, which increases the rigidity of adjacent units to prevent rotational disorder and lower the reorganization energy, leading to improved carrier mobility and optimized film morphology. In this work, fused‐ring ladder‐type indacenodithiophene and indacenodithieno[3,2‐b]thiophene are used as D units, benzodithiophene‐4,8‐dione as the A unit, and thienothiophene as a π‐bridge to form the D–A polymers PBDTT and PBTTT, respectively. Both polymers exhibit favorable properties as HTMs including suitable energy levels, high hole mobility, and excellent film quality. Both dopant‐free HTMs endow n‐i‐p PVSCs with promising performance and stability. A maximum power conversion efficiency of 20.28% is achieved for PBDTT‐based devices, which is among the highest values reported to date.
Herein, an organic fluorophore termed NLAC is introduced into 2D hybrid perovskites with wide band gap (>3.54 eV) to give a green emission with quantum yield up to 81%. The highly efficient luminescence is ascribed to avoiding the aggregation of NLAC and formation of an inorganic free exciton which is easy to thermally quench. On this basis, a new strategy to generate efficient white emission with afterglow has been proposed by codoping a short-wavelength fluorophore and long-wavelength phosphor into 2D organic− inorganic hybrid perovskites (OIHPs). As a result, a single-component white-light-emitting material PEPC-3N based on NLAC with CIE of (0.33, 0.36) and quantum yield up to 43% can be obtained. Interestingly, PEPC-3N shows a dual-color organic afterglow and excitation-wavelength-dependent emission, consequently forming a switch between green fluorescence and yellow afterglow. This unique performance indicates PEPC-3N has huge potential in afterglow WLEDs and information storage.
In conventional n–i–p perovskite solar cells (PVSCs), electron donor (D)–acceptor (A) polymers have been found to be potential substitutes for doped spiro‐based small molecule hole‐transporting materials (HTMs) due to their excellent performance in hole mobility, film formability, and stability. Herein, a benzo[1,2‐b:4,5‐b′]dithiophene (BDT)‐benzodithiophene‐4,8‐dione (BDD) copolymer PBDB‐Cz is developed by employing carbazole as the conjugated side chain of BDT. PBDB‐O and PBDB‐T with alkoxy and thiophene as the side chain of BDT, respectively, are also synthesized and studied for comparison. The synergistic effect of the carbazole side chain and the BDT‐BDD backbone to promote hole transport properties is found in PBDB‐Cz. The carbazole side chain enhances both coplanarity and interaction of polymer chains, while simultaneously deepening energy levels and improving the hole mobility of the polymeric HTM. Consequently, PBDB‐Cz outperforms two counterparts, exhibiting a promising power conversion efficiency (PCE) of 22.06%. Notably, the PBDB‐Cz also improves the device stability, and the devices can retain more than 90% of their initial PCEs after being stored at ambient conditions for 100 days. To the best of the authors’ knowledge, this is the first report to incorporate carbazole into D–A polymeric HTM by side chain engineering.
Two-dimensional (2D) white-light-emitting hybrid perovskites (WHPs) are promising active materials for single-component white-light-emitting diodes (WLEDs) driven by UV. However, the reported WHPs exhibit low quantum yields (≤9%) and low color rendering index (CRI) values less than 85, which does not satisfy the demand of solid-state lighting applications. In this work, we report a series of mixed-halide 2D layered WHPs (CHCHNH)PbBr Cl (0 < x < 4) obtained from the phenethylammonium cation. Unlike the reported WHPs including (CHCHNH)PbCl, the mixed-halide perovskites display morphology-dependent white emission for the different extents of self-absorption. Additionally, the amount of Br has a huge influence on the photophysical properties of mixed-halide WHPs. With the increasing content of Br, the quantum yields of WHPs increase gradually from 0.2 to 16.9%, accompanied by tunable color temperatures ranging from 4000 K ("warm" white light) to 7000 K ("cold" white light). When applied to the WLEDs, the mixed-halide perovskite powders exhibit tunable white electroluminescent emission with very high CRI of 87-91.
Organic afterglow materials (OAMs) with a lifetime longer
than 0.1 s have recently received much attention for their fascinating
properties meeting the critical requirements of applications in newly
emerged technologies. However, the development of OAMs lags behind
for their low luminescence efficiency. Usually, enhancing the phosphorescence
efficiency of organic materials causes a short lifetime. Here, we
report two kinds of OAMs, two-dimensional (2D) layered organic–inorganic
hybrid zinc bromides (PEZB-NTA and PEZB-BPA), obtained in an environmentally
friendly ethanol solvent by a low-temperature solution method. They
display highly efficient and persistent luminescence in air in both
crystals and thin films with phosphorescence quantum yields up to
42% in crystals and 27% in films. For OAMs, the two quantum yields
are the highest values ever reported for crystals and films. Due to
the excellent crystalline and film-forming ability, PEZB-NTA and PEZB-BPA
in ethanol can be used as inks to construct patterns on various rigid
and flexible substrates, including paper, iron, plastic, marble, tin
foil, and cloth. Consequently, the novel OAMs show great application
prospects in the fields of anti-counterfeiting and information storage
because of their economic synthesis, solution processing, and easy
operation.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.