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[1] In this study we used LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry) to determine U-Pb ages of 5 zircon samples of known age ($1800 Ma to $50 Ma) in order to determine the reproducibility, precision, and accuracy of this geochronologic technique. This work was performed using a ThermoFinnigan Element2 magnetic sector double-focusing ICP-MS coupled with a New Wave Research UP-213 laser system. The laser ablation pit sizes ranged from 30 to 40 mm in diameter. Laserinduced time-dependent fractionation is corrected by normalizing measured ratios in both standards and samples to the beginning of the analysis using the intercept method. Static fractionation, including those caused during laser ablation and due to instrumental discrimination, is corrected using external zircon standards. Total uncertainty for each laser analysis of an unknown is combined quadratically from the uncertainty in the measured isotope ratios of the unknown and the uncertainty in the fractionation factors calculated from the measurement of standards. For individual analyses we estimate that the accuracy and precision are better than 4% at the 2 sigma level, with the largest contribution in uncertainty from the measurement of the standards. Accuracy of age determinations in this study is on the order of 1% on the basis of comparing the weighted average of the LA-ICP-MS determinations to the TIMS ages. Due to unresolved contributions to uncertainty from the lack of a common Pb correction and from potential matrix effects between standards and unknowns, however, this estimate cannot be universally applied to all unknowns. Nevertheless, the results of this study provide an example of the type of precision and accuracy that may be possible with this technique under ideal conditions. In summary, the laser ablation technique, using a magnetic sector ICP-MS, can be used for the U-Pb dating of zircons with a wide range of ages and is a useful complement to the established TIMS and SHRIMP techniques. This technique is especially well suited to reconnaissance geochronologic and detrital zircon studies.

We are grateful to Mr. Bryan Yap, President of Lepanto Consolidated Mining Company, for permission to conduct this study in the Mankayan district, for providing access to the air magnetic and radiometric survey results, and for permission to publish the outcome of this study. This work is part of AMIRA Project P765, completed in December, 2006, at CODES, University of Tasmania. The project was sponsored by Anglo American, Anglo Gold Ashanti, Gold Fields, Newcrest, Newmont, Placer Dome, and Teck Cominco, as well as Barrick in the final year, with additional funding provided by the Australian Research Council. We acknowledge the discussion and ideas provided by representatives of the sponsoring companies, and assistance by the AMIRA research coordinator Alan Goode. We thank Lyndon Bradish and Froilan Conde, plus many other Lepanto staff, including Bene, Danny, Ed, Louie, Perfecto, Perry, Ric, and Willy, for their assistance, and Dave Braxton for help in the field. Paddy Waters of Anglo American Philippines generously provided logistic support and funding for some of the whole-rock geochemical analyses. We appreciate the help from CODES staff, including Simon Stephens for sample preparation, Sarah Gilbert and Leonid Danyushevsky for LA-ICP-MS analyses, and June Pongratz for report preparation. We thank Roger Stoffregen for comments on an early version of the manuscript, and John Thompson and Raymond Jannas for useful reviews.

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publisher: Elsevier articletitle: The chlorite proximitor: A new tool for detecting porphyry ore deposits journaltitle: Journal of Geochemical Exploration articlelink: http://dx.doi.org/10.1016/j.gexplo.2015.01.005 content_type: article copyright: Crown copyright © 2015 Published by Elsevier B.V.Published open acces

We report sulfur isotopic compositions of sulfi des of various paragenetic stages in the giant Sukhoi Log sediment-hosted orogenic Au deposit in Russia. The overall mean value and the signifi cant variability in early pyrite indicate that the sulfur was from the reduction of seawater sulfate. The later generations of sulfi de have δ 34 S values in successively smaller ranges, coincident with the mode that is around the median value of the whole data set. Together with textural evidence, sulfi de trace element data, and gold occurrence, the data demonstrate that metamorphism has gradually homogenized the early sulfur, accompanied by the segregation of quartz and the release of Au from the lattice of early pyrite and its reprecipitation as inclusions in later pyrite. The S isotopic compositions of sulfi des in Sukhoi Log, and many other major orogenic Au deposits hosted in sedimentary rocks of various ages, show a pattern generally parallel to the seawater sulfate curve through geologic time, indicating that the sulfur in most sediment-hosted orogenic Au deposits was probably also originally from the reduction of seawater sulfate. We conclude that sulfi dation and gold mineralization in many sediment-hosted orogenic gold deposits was early during basin evolution when seawater was the principal active fl uid, rather than later, during or after basin inversion, as proposed in current models.