[1] In this study we used LA-ICP-MS (laser ablation-inductively coupled plasma-mass spectrometry) to determine U-Pb ages of 5 zircon samples of known age ($1800 Ma to $50 Ma) in order to determine the reproducibility, precision, and accuracy of this geochronologic technique. This work was performed using a ThermoFinnigan Element2 magnetic sector double-focusing ICP-MS coupled with a New Wave Research UP-213 laser system. The laser ablation pit sizes ranged from 30 to 40 mm in diameter. Laserinduced time-dependent fractionation is corrected by normalizing measured ratios in both standards and samples to the beginning of the analysis using the intercept method. Static fractionation, including those caused during laser ablation and due to instrumental discrimination, is corrected using external zircon standards. Total uncertainty for each laser analysis of an unknown is combined quadratically from the uncertainty in the measured isotope ratios of the unknown and the uncertainty in the fractionation factors calculated from the measurement of standards. For individual analyses we estimate that the accuracy and precision are better than 4% at the 2 sigma level, with the largest contribution in uncertainty from the measurement of the standards. Accuracy of age determinations in this study is on the order of 1% on the basis of comparing the weighted average of the LA-ICP-MS determinations to the TIMS ages. Due to unresolved contributions to uncertainty from the lack of a common Pb correction and from potential matrix effects between standards and unknowns, however, this estimate cannot be universally applied to all unknowns. Nevertheless, the results of this study provide an example of the type of precision and accuracy that may be possible with this technique under ideal conditions. In summary, the laser ablation technique, using a magnetic sector ICP-MS, can be used for the U-Pb dating of zircons with a wide range of ages and is a useful complement to the established TIMS and SHRIMP techniques. This technique is especially well suited to reconnaissance geochronologic and detrital zircon studies.
[1] The ''laser ablation split stream'' (LASS) technique is a powerful tool for mineral-scale isotope analyses and in particular, for concurrent determination of age and Hf isotope composition of zircon. Because LASS utilizes two independent mass spectrometers, a large range of masses can be measured during a single ablation, and thus, the same sample volume can be analyzed for multiple geochemical systems. This paper describes a simple analytical setup using a laser ablation system coupled to a singlecollector (for U-Pb age determination) and a multicollector (for Hf isotope analyses) inductively coupled plasma mass spectrometer (MC-ICPMS). The ability of the LASS for concurrent Hf 1 age technique to extract meaningful Hf isotope compositions in isotopically zoned zircon is demonstrated using zircons from two Proterozoic gneisses from northern Idaho, USA. These samples illustrate the potential problems associated with inadvertently sampling multiple age and Hf components in zircons, as well as the potential of LASS to recover meaningful Hf isotope compositions. We suggest that such inadvertent sampling of differing age and Hf components can be a significant cause of excess scatter in Hf isotope analyses and demonstrate that the LASS approach offers a robust solution to these issues. The veracity of the approach is demonstrated by accurate analyses of 10 reference zircons with well-characterized age and Hf isotopic composition, using laser spot diameters of 30 and 40 mm. In order to expand the database of high-precision Lu-Hf isotope analyses of reference zircons, we present 27 new isotope dilution-MC-ICPMS Lu-Hf isotope measurements of five U-Pb zircon standards: FC1, Temora, R33, QGNG, and 91500.
The western Idaho shear zone is a major, lithospheric-scale structure separating accreted terranes of the Blue Mountains from continental North America. We document the occurrence of the western Idaho shear zone in West Mountain, west-central Idaho. Rocks deformed by the western Idaho shear zone at West Mountain are dominantly orthogneisses, although exposures on West Mountain containing screens of metamorphosed sedimentary rocks are also present. Steeply E-dipping, N-NNE-oriented foliations and downdip lineations characterize the fabric in the orthogneisses, consistent with dextral transpressional kinematics. The foliation orientation changes from 005° to 024° from the northern to the southern part of the field area, and this is interpreted to reflect a primary along-strike variation in the orientation of the western Idaho shear zone. The westernmost unit in West Mountain (Four Bit Creek tonalite) has a U-Pb zircon age of 101 ± 3.0 Ma, yet it is only weakly deformed. We interpret this unit to have been emplaced pretectonically, thus constraining the initiation of the western Idaho shear zone. The youngest unit at West Mountain is the undeformed Rat Creek granite (88.2 ± 3.3 Ma). U-Pb analyses of zircons from ortho gneisses at West Mountain span ages of 111-91 Ma, indicating both precursory and continuous magmatism coeval with western Idaho shear zone deformation. Two Lu-Hf garnet isochron ages, 97.3 ± 0.7 Ma and 99.5 ± 1.4 Ma, are interpreted to indicate peak metamorphism during western Idaho shear zone deformation. Geochemical analyses suggest that the westernmost exposed orthogneiss units are dominantly derived from continental material in West Mountain, and yet there is also evidence for a component of accreted terrane rocks at depth east of the western Idaho shear zone.
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