Dye-sensitized solar cells (DSSCs) are regarded as prospective solar cells for the next generation of photovoltaic technologies and have become research hotspots in the PV field. The counter electrode, as a crucial component of DSSCs, collects electrons from the external circuit and catalyzes the redox reduction in the electrolyte, which has a significant influence on the photovoltaic performance, long-term stability and cost of the devices. Solar cells, dye-sensitized solar cells, as well as the structure, principle, preparation and characterization of counter electrodes are mentioned in the introduction section. The next six sections discuss the counter electrodes based on transparency and flexibility, metals and alloys, carbon materials, conductive polymers, transition metal compounds, and hybrids, respectively. The special features and performance, advantages and disadvantages, preparation, characterization, mechanisms, important events and development histories of various counter electrodes are presented. In the eighth section, the development of counter electrodes is summarized with an outlook. This article panoramically reviews the counter electrodes in DSSCs, which is of great significance for enhancing the development levels of DSSCs and other photoelectrochemical devices.
Electrochemically reversible redox couples that embrace more electron transfer at a higher potential are the eternal target for energy storage batteries. Here, we report a four-electron aqueous zinc-iodine battery by activating the highly reversible I2/I+ couple (1.83 V vs. Zn/Zn2+) in addition to the typical I−/I2 couple (1.29 V). This is achieved by intensive solvation of the aqueous electrolyte to yield ICl inter-halogens and to suspend its hydrolysis. Experimental characterization and modelling reveal that limited water activity and sufficient free chloride ions in the electrolyte are crucial for the four-electron process. The merits of the electrolyte also afford to stabilize Zn anode, leading to a reliable Zn-I2 aqueous battery of 6000 cycles. Owing to high operational voltage and capacity, energy density up to 750 Wh kg−1 based on iodine mass was achieved (15–20 wt% iodine in electrode). It pushes the Zn-I2 battery to a superior level among these available aqueous batteries.
As game‐changers in the photovoltaic community, perovskite solar cells are making unprecedented progress while still facing grand challenges such as improving lifetime without impairing efficiency. Herein, two structurally alike polyaromatic molecules based on naphthalene‐1,8‐dicarboximide (NMI) and perylene‐3,4‐dicarboximide (PMI) with different molecular dipoles are applied to tackle this issue. Contrasting the electronically pull–pull cyanide‐substituted PMI (9CN‐PMI) with only Lewis‐base groups, the push–pull 4‐hydroxybiphenyl‐substituted NMI (4OH‐NMI) with both protonic and Lewis‐base groups can provide better chemical passivation for both shallow‐ and deep‐level defects. Moreover, combined theoretical and experimental studies show that the 4OH‐NMI can bind more firmly with perovskite and the polyaromatic backbones create benign midgap states in the excited perovskite to suppress the damage by superoxide anions (energetic passivation). The polar and protonic nature of 4OH‐NMI facilitates band alignment and regulates the viscosity of the precursor solution for thicker perovskite films with better morphology. Consequently, the 4OH‐NMI‐passivated perovskite films exhibit reduced grain boundaries and nearly three‐times lower defect density, boosting the device efficiency to 23.7%. A more effective design of the passivator for perovskites with multi‐passivation mechanisms is provided in this study.
Using poly(N-methyl-4-vinyl-pyridine iodide), N-methyl-pyridine iodide and iodine, a solid polymer electrolyte with conductivity of 6.41 mS/cm is prepared. On the basis of a solid polymer electrolyte, a conducting graphite layer, a KI block layer, and a vacuum assembling technique, we achieve an all-solid-state dye-sensitized solar cell with total photoelectric conversion efficiency of 5.64% under AM 1.5 simulated solar light (100 mW/cm2) illumination.
In this work, we have developed multiple-armed DNA tetrahedral nanostructures (TDNs) for dual-modality in vivo imaging using near-infrared (NIR) fluorescence and single-photon emission computed tomography (SPECT). We found that the presence of arm strands in TDNs remarkably enhanced their in vitro stability, allowing them to stay intact for at least 12 h in serum. By using NIR fluorescence imaging, we evaluated in mice the pharmacokinetics of TDNs, which exhibited distinctly different in vivo biodistribution patterns compared with those of double-stranded (ds)DNA. We also noticed that TDNs had twofold longer circulation time in the blood system than that of dsDNA. With the use of multiple-armed TDNs, we could precisely anchor an exact number of functional groups including tumor-targeting folic acid (FA), NIR emitter Dylight 755, and radioactive isotope (99m)Tc on prescribed positions of TDNs, which showed the capability of targeted imaging ability in cancer cells. Furthermore, we realized noninvasive tumor-targeting imaging in tumor-bearing mice by using both NIR and SPECT modalities.
Low‐temperature‐processed perovskite solar cells (PSCs), which can be fabricated on rigid or flexible substrates, are attracting increasing attention because they have a wide range of potential applications. In this study, the stability of reduced graphene oxide and the ability of a poly(triarylamine) underlayer to improve the quality of overlying perovskite films to construct hole‐transport bilayer by means of a low‐temperature method are taken advantage of. The bilayer is used in both flexible and rigid inverted planar PSCs with the following configuration: substrate/indium tin oxide/reduced graphene oxide/polytriarylamine/CH3NH3PbI3/PCBM/bathocuproine/Ag (PCBM = [6,6]‐phenyl‐C61‐butyric acid methyl ester). The flexible and rigid PSCs show power conversion efficiencies of 15.7 and 17.2%, respectively, for the aperture area of 1.02 cm2. Moreover, the PSC based the bilayer shows outstanding light‐soaking stability, retaining ≈90% of its original efficiency after continuous illumination for 500 h at 100 mW cm−2.
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