Formation of the semiconductor/dielectric double-layered
films
via vertical phase separations from polymer blends is an effective
method to fabricate organic thin-film transistors (OTFTs). Here, we
introduce a simple one-step processing method for the vertical phase
separation of poly(3-hexylthiophene-2,5-diyl) (P3HT) and poly(methyl
methacrylate) (PMMA) blends in OTFTs and their applications for high-performance
nitrogen dioxide (NO2) sensors. Compared to the conventional
two-step coated OTFT sensors, one-step processed devices exhibit a
great enhancement of the responsivity from 116 to 1481% for 30 ppm
NO2 concentration and a limit of detection of ∼0.7
ppb. Studies of the microstructures of the blend films and the electrical
properties of the sensors reveal that the devices formed by the one-step
vertical phase separation have better capability for the adsorption
of NO2 molecules. Moreover, a careful adjustment of the
blend ratio between P3HT and PMMA can further improve the performance
of the NO2 sensors, ranging from sensitivity to selectivity
and to the ability of recovery. This simple one-step processing method
demonstrates a potential possibility for developing high-performance,
low-cost, and large-area OTFT gas sensors.
This Letter reports a polymer optical fiber (POF) based large strain sensor based on the multimode interference (MMI) theory for the application of structural health monitoring. A section of POFs is sandwiched between two silica single mode fibers to construct a single-mode-multimode-single-mode structure that produces a MMI spectrum. The strain sensing mechanism of the device was investigated and experimentally verified. A large dynamic range of 2×10(4) με (2%) and a detection limit of 33 µε have been demonstrated.
In
recent years, polymer-based dielectric capacitors have attracted
much more attention due to the advantages of excellent flexibility,
light weight, and high power density. However, most studies focus
on energy storage performances of polymer-based dielectrics at room
temperature, and there have been relatively fewer investigations on
polymer-based dielectrics working under high-temperature conditions,
which is much closer to the practical applications. Besides, dielectric
capacitors operating in a high-temperature environment require excellent
temperature stability of structure and performance. In this paper,
high-temperature-resistant polyimide (PI) is selected as the matrix
material, and 0.5Ba(Zr0.2Ti0.8)O3–0.5(Ba0.7Ca0.3)TiO3 (BZT–BCT)
nanofibers are used as the filling phase. By analyzing the energy
storage behaviors of BZT–BCT/PI composites at different temperatures,
it can be found that when the doping content of BZT–BCT nanofibers
is more than 1 vol % the dielectric strength of the composites drops
sharply when the temperature increases from 25 to 150 °C, resulting
in serious deterioration of energy storage properties. On the basis
of this, a composite film with a sandwich structure has been designed,
where BZT–BCT/PI with different volume fractions is the intermediate
layer and hexagonal boron nitride (h-BN) with good thermal and insulating
properties is introduced in the top and bottom layers with a content
of 5 vol %. Consequently, the results have shown that the energy storage
properties of the constructed sandwiched dielectric composite films
exhibit excellent temperature stability. The maximum field strength
of the composite film with a BZT–BCT content of 1 vol % in
the intermediate layer is 360 and 350 kV/mm under temperatures of
25 and 150 °C, and the storage density is 2.3 and 1.83 J/cm3 respectively.
A combined treatment using medication and electrostimulation increases its effectiveness in comparison with one treatment alone. However, the organic integration of two strategies in one miniaturized system for practical usage has seldom been reported. This article reports an implantable electronic medicine based on bioresorbable microneedle devices that is activated wirelessly for electrostimulation and sustainable delivery of anti-inflammatory drugs. The electronic medicine is composed of a radio frequency wireless power transmission system and a drug-loaded microneedle structure, all fabricated with bioresorbable materials. In a rat skeletal muscle injury model, periodic electrostimulation regulates cell behaviors and tissue regeneration while the anti-inflammatory drugs prevent inflammation, which ultimately enhance the skeletal muscle regeneration. Finally, the electronic medicine is fully bioresorbable, excluding the second surgery for device removal.
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