Strong metal‐support interaction (SMSI) is crucial for supported catalysts in heterogeneous catalysis. Here is the first report on strong metal phosphide‐phosphate support interaction (SMPSI). The key to SMPSI is the activation of P species on the support, which leads to simultaneous generation of metal phosphide nanoparticles (NPs) and core–shell nanostructures formed by support migration onto the NPs. The encapsulation state of metal phosphide and charge transfer are identical to those of classical SMSIs and can be optimally regulated. Furthermore, the strong interactions of Co2PL/MnP‐3 not only significantly enhance the anti‐oxidation and anti‐acid capability of non‐noble metal but also exhibit excellent catalytic activity and stability toward hydrogenating a wide range of compounds into value‐added fine chemicals with 100% selectivity, which is even better than Pd/C and Pt/C. The SMPSI construction can be generally extended to other systems such as Ni2PL/Mn3(PO4)2, Co2PL/LaPO4, and CoPL/CePO4. This study provides a new approach for the rational design of advanced non‐noble metal catalysts and introduce a novel paradigm for the strong interaction between NPs and support.
The analyzing power A y (θ ) for neutron elastic scattering from 12 C has been measured for 33 neutron energies between E n = 2.2 and 8.5 MeV in the angular range from 25 • to 145 • in the laboratory system. The primary motivation for these measurements is the need for an accurate knowledge of A y (θ) for 12 C(n, n) 12 C elastic scattering to enable corrections to high-precision neutron-proton and neutron-deuteron A y (θ) data in the neutronenergy range below E n = 30 MeV. In their own right, 12 C(n, n) 12 C A y (θ) data are of crucial importance for improving both the parametrization of n-12 C scattering and our knowledge of the level scheme of 13 C. The present A y (θ ) data are compared with published data and previous phase-shift-analysis results.
Objective:To determine whether the effectiveness of core stability exercises correlates with the severity of spinal stenosis in patients with degenerative lumbar spinal stenosis.Methods:Forty-two patients with degenerative lumbar spinal stenosis treated in the department of orthopedics of our hospital between May 2013 and January 2016 were included in the study. All the patients performed core stability exercises once daily for six weeks, and the clinical outcomes were evaluated using Japanese Orthopaedic Association (JOA) score and self-reported walking capacity. The anteroposterior osseous spinal canal diameter was measured to evaluate the severity of spinal stenosis. The correlation between the stenosis degree and the differences of Japanese Orthopaedic Association score or self-reported walking capacity at baseline and after treatment were analyzed.Results:The patients were divided into three groups according to the spinal stenosis degree. In the three groups, there was no significant difference in JOA or self-reported walking distance at baseline (p>0.05) and after treatment (p>0.05). The JOA scores and self-reported walking distance were significantly increased after treatment (p<0.05) in any of the three groups when compared to the baseline. Also, there was no significant correlation between the stenosis degree and the difference of JOA (p>0.05) or self-reported walking distance (p>0.05).Conclusion:There was no significantcorrelation between the effectiveness of core stability exercises and the severity of spinal stenosis in patients with degenerative lumbar spinal stenosis.
Data for σ (θ) and A y (θ ) previously obtained at the Triangle Universities Nuclear Laboratory for 120 Sn(n, n) are combined with other measurements of σ (θ) and A y (θ ) to create an elastic-scattering database from 9.9 to 24 MeV. In addition, relatively recent high-accuracy measurements of the neutron total cross section σ T for Sn from 5 to 80 MeV are combined with earlier σ T data to form a detailed σ T database from 0.24 to 80 MeV. All of these data are analysed in the framework of a dispersive optical model (DOM). The DOM is extended to negative energies to investigate properties of single-particle and single-hole bound states. The DOM also is used in calculations of compound-nucleus contributions to σ (θ), so that DOM predictions can be compared to σ (θ) measurements. Excellent agreement is obtained for the entire set of scattering data from 0.4 to 24 MeV, and for σ T values from 0.05 to 80 MeV. Calculations of bound-state quantities are compared to values derived from experiment for energies down to −15 MeV. Reasonable agreement for the binding energies is achieved, while the predicted spectroscopic factors disagree somewhat with the values found in stripping and pickup experiments. Finally, the DOM is modified to investigate two features (volume absorption that is asymmetric about the Fermi energy and zero absorption in the vicinity of the Fermi energy) that have been ignored in many DOM models. These modifications have little effect on the agreement of the calculations with the scattering data or with the bound-state quantities.
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