Polyphosphazenes (PPNs) belong to organic‐inorganic hybrid polymeric skeletal materials suitably fabricated via precipitation or condensation polymerization and self‐assembly approaches. Organic moieties with two and three −NH2 or −OH functionalities inherit subsequent ordered 2D and 3D arrangements of the atoms and molecules to attain the morphologies such as nanotubes, nano/micro‐spheres, fibers, nanosheets, and covalent organic frameworks (COFs). Auto‐doping is a strategic feature of PPN materials to originate binary‐, ternary‐, and quaternary‐doped carbon frameworks and graphitic carbon nitride (g‐C3N4) upon direct pyrolysis in an inert environment. Hollow carbon spheres provides a good range of surface areas (ca. 755–3673 m2/g) with enormous active sites and hierarchical channels for the effective flow of electrolyte ions, which make them a good choice for solid‐state batteries and supercapacitors; structural irregularities and imperfections offer surface‐adsorbed breakdown of water and open new horizons for water splitting through hydrogen evolution, oxygen evolution and oxygen reduction with the lowest half‐wave (E1/2) potential when compared to Pt/C‐ and Pt/C+RuO2‐based electrocatalysts.
Covalent inorganic-organic hybrid frameworks (CIOFs) comprised of inorganic heterocycles covalently linked to organic building blocks are a relatively unexplored and fertile area of research compared to the covalent organic frameworks....
In the present study, biological method was opted to synthesize ZnO NPs from Rumex dentatus plant. 0.1 M solution of zinc nitrate hexahydrate is mixed with the aqueous solution of R. dentatus plant leaves extract. The proportion of each solution was 1:1. Extract of plant leaves act as reducing agent. Firstly, the color changed from dark green to brown was observed and precipitates of light brown color appeared. Characterization of produced ZnO NPs was done using UV–Visible spectroscopy, scanning electron microscopy (SEM), energy dispersive X-rays (EDX) and X-ray diffraction (XRD) spectroscopy. The prepared ZnO NPS shows maximum absorption at 373 nm, in UV–Visible range. The shape of synthesized ZnO NPs is displayed by SEM. XRD analysis explains the average size of NPs is 6.19 nm. EDX tells about the percentage composition of synthesized ZnO NPs. Antibacterial analysis declared the NPs as good antibacterial agents. Photocatalytic activity of ZnO NPs was done using methyl orange dye. It was concluded that ZnO NPs can degrade toxic pollutants especially dyes.
Since ancient times, medicinal plants have been used as traditional medicine to treat a variety of ailments. Aloe vera (AV) gel’s therapeutic potential is one of the most effective approach in the fabrication of functional materials. The current study aimed to prepare the AV and chitosan (CS) membranes using various cross-linkers that were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform-infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), and ultraviolet-visible (UV-Visible) techniques, as well as swelling ratio and antimicrobial studies. SEM analysis revealed that the membrane is porous, with interconnected pores. The inclusion of AV contents in the membrane improved thermal stability and crystallinity. The swelling ratio of the ACPG-3 membrane with a 2:1 CS to AV ratio was 366%. The membranes showed promising antimicrobial activity against Escherichia coli, Staphylococcus aureus, Bacillus subtilis, and Pasteurella multocida strains. The findings revealed that polymeric CS/AV membranes have effective potential for use in the biomedical field.
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