In order to understand the behavior of COS in a ZnO
desulfurization reactor, the reaction between
ZnO and COS was studied in the presence of gases which compose a
coal-derived gas. The
behavior of COS in the reaction zone of a ZnO packed bed can be
predicted as follows: H2S in
coal-derived gas reacts more easily with ZnO than COS; most of COS is
converted to H2S by
catalytic hydrolysis and then reacts with ZnO, although a part of COS
may react directly with
ZnO; H2 accelerates the conversion of COS to
H2S; the water−gas shift reaction accelerates
the
reaction between ZnO and COS; and CO2 does not affect the
reaction.
Low-temperature hydrothermal treatment of waste biomass (sawdust) was performed using an autoclave at various temperatures of 180, 250, and 280 °C for 15 min and 60 min. The oil product was obtained from both liquid and solid portions of reaction products from the autoclave, and the composition of oil products was investigated separately. At high reaction temperature, i.e., 250 °C and 280 °C, the longer reaction time led to decreased oil yield; at low reaction temperature (180 °C), the oil yield was found to increase with the increase of reaction time. The oil1 (extracted from the liquid portion) consists of low-boiling-point compounds, whereas oil2 (extracted from the solid portion) contained both low-and high-boiling-point oxygenated hydrocarbons. Ca(OH) 2 was found to be effective on liquefaction of biomass in terms of both oil yield and composition. The volatility distribution of oxygenated hydrocarbons in oil1 and oil2 was studied by using a C-NP gram which can be used as a tool for characterizing biomass-derived oil products.
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