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Microencapsulation is widely used to minimize the oxidation of fish oil products. This study compared the effects of different drying methods, for example, spray drying (SD), freeze drying (FD), and spray freeze drying (SFD) on the microencapsulation of fish oil. Spray drying (SD) is the most common method for producing fish oil microcapsules, and it has low operation cost and short processing time, while the product yield and quality are poor. Freeze drying (FD) can be used to produce oil microcapsules with high quality, but it takes long time and high overall cost for drying. Spray freeze drying (SFD) is a new method for the preparation of microcapsules, which combines the SD and FD processes to obtain high quality powder. The yield of powder reached 95.07% along with porous structure by SFD. The stability and slow-release property of SFD products were better than those of SD and FD, which showed that SFD improved product storage stability and potential digestibility.

With the completion of the BeiDou Global Navigation Satellite System (BDS-3), the multi-system precise point positioning ambiguity resolution (PPP-AR) has been realized. The satellite phase fractional cycle bias (FCB) is a key to the PPP-AR. Compared to the combined ionosphere-free (IF) model, the undifferenced and uncombined (UDUC) model retains all the information from the observations and can be easily extended to arbitrary frequencies. However, the FCB is difficult to apply directly to the UDUC model. An observable-specific signal bias (OSB) can interact directly with the original observations, providing complete flexibility for PPP-AR for multi-frequency multi-GNSS. In this study, the OSB product generation for the GPS (G), Galileo (E), and BDS-3 (C) systems is performed using 117 globally distributed multi-GNSS experiment (MGEX) stations, and their performances are evaluated. Then, the PPP-AR comparison and analysis of the two positioning models of the UDUC and IF are conducted. The results show that the stability of OSB products of the three systems is better than 0.05 ns. For the precise point positioning (PPP) ambiguity fixed solution, with comparable positioning accuracy and convergence time to the products of both the Wuhan University (WUM) and the Centre National d’Etudes Spatials (CNES) institutions, an average fixed-ambiguity rate is over 90%. Compared to the PPP float solution, the PPP-AR has the most significant improvement in positioning accuracy in the E-direction. The average improvements in the positioning accuracy under the IF and UDUC models in the static and kinematic modes are higher than 45% and 40%, respectively. The convergence times of the IF and UDUC models are improved on average by 48% and 60% in the static mode and by 40% and 55% in the kinematic mode, respectively. Among the IF and UDUC positioning models, the former has slightly better positioning accuracy and convergence time than the latter for the PPP float solution. However, both models have comparable positioning accuracy and convergence time after the PPP-AR. The GCE multi-system combination is superior to other system combinations. The average convergence time for the static PPP fixed solution is 8.5 min, and the average convergence time for the kinematic PPP fixed solution is 16.4 min.

Multi-frequency observations are now available from GNSSs, thereby bringing new opportunities for precise point positioning (PPP). However, they also introduce new challenges, such as inter-frequency clock bias (IFCB) between the new frequencies and the original dual-frequency observations due to triple-frequency observations, which severely impact the PPP. In this paper, we studied the estimation and correction methods of uncombined inter-frequency clock bias of GPS, BDS-3, and Galileo, analyzed the time-varying characteristics and short-term stability of IFCB, and analyzed the influence of IFCB on the positioning of the GPS, BDS-3, and Galileo, based on a triple-frequency un-differential non-combined PPP model. The obtained results show that the amplitude of Block IIF satellites of the GPS can reach up to 10–20 cm, and the IFCB in BDS-3, Galileo, and GPS Block III satellites can be neglected. After correction by IFCB, the 3D positioning accuracy of the GPS triple-frequency PPP was 1.73 cm and 4.75 cm in the static and kinematic modes, respectively, while the convergence time was 21.64 min and 39.61 min. Compared with the triple-frequency GPS PPP without any correction with IFCB, the static and kinematic 3D positioning accuracy in this work was improved by 27.39% and 17.34%, and the corresponding convergence time was improved by 10.55% and 15.22%, respectively. Furthermore, the delayed IFCB was also used for positioning processing, and it was found that a positioning performance comparable to that of the same day can be obtained. The standard deviation of IFCB for a single satellite was found to be no more than 1 cm, when the IFCB value of a neighboring day was subtracted from the IFCB value of same day, which proves the short-term stability of IFCB.

Visible light was used as a readily available and renewable clean energy source for the green and metal catalyst free synthesis of quinazolin-4(3H)-ones. High and excellent yields of the desired products were obtained with good functional group tolerance.

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