Fluorine-contained polymers, which have been widely used in highly efficient polymer solar cells (PSCs), are rather costly due to their complicated synthesis and low yields in the preparation of components. Here, the feasibility of replacing the critical fluorine substituents in high-performance photovoltaic polymer donors with chlorine is demonstrated, and two polymeric donors, PBDB-T-2F and PBDB-T-2Cl, are synthesized and compared in parallel. The synthesis of PBDB-T-2Cl is much simpler than that of PBDB-T-2F. The two polymers have very similar optoelectronic and morphological properties, except the chlorinated polymer possess lower molecular energy levels than the fluorinated one. As a result, the PBDB-T-2Cl-based PSCs exhibit higher open circuit voltage (V ) than the PBDB-T-2F-based devices, leading to an outstanding power conversion efficiency of over 14%. This work establishes a more economical design paradigm of replacing fluorine with chlorine for preparing highly efficient polymer donors.
Fabricating organic solar cells (OSCs) with a tandem structure has been considered an effective method to overcome the limited light absorption spectra of organic photovoltaic materials. Currently, the most efficient tandem OSCs are fabricated by adopting fullerene derivatives as acceptors. In this work, we designed a new non-fullerene acceptor with an optical band gap (E) of 1.68 eV for the front subcells and optimized the phase-separation morphology of a fullerene-free active layer with an E of 1.36 eV to fabricate the rear subcell. The two subcells show a low energy loss and high external quantum efficiency, and their photoresponse spectra are complementary. In addition, an interconnection layer (ICL) composed of ZnO and a pH-neutral self-doped conductive polymer, PCP-Na, with high light transmittance in the near-IR range was developed. From the highly optimized subcells and ICL, solution-processed fullerene-free tandem OSCs with an average power conversion efficiency (PCE) greater than 13% were obtained.
A novel non-fullerene acceptor, possessing a very low bandgap of 1.34 eV and a high-lying lowest unoccupied molecular orbital level of -3.95 eV, is designed and synthesized by introducing electron-donating alkoxy groups to the backbone of a conjugated small molecule. Impressive power conversion efficiencies of 8.4% and 10.7% are obtained for fabricated single and tandem polymer solar cells.
With rapid development for tens of years, organic solar cells (OSCs) have attracted much attention for their potential in practical applications. As an important photovoltaic parameter, the fill factor (FF) of OSCs stands for the effectiveness of charge generation and collection, which significantly depends on the properties of the interlayer and active layer. Here, a facile and effective strategy to improve the FF through hole-transporting layer (HTL) modification is demonstrated. By mixing WO nanoparticles with a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) emulsion, the surface free energy of the HTL is improved and the morphology of the active layer is optimized. Benefiting from increased carrier lifetime, a device based on WO :PEDOT:PSS HTL exhibits a boosted performance with an FF of 80.79% and power conversion efficiency of 14.57% PCE. The results are certified by the National Institute of Metrology (NIM), which, to date, are the highest values in this field with certification. This work offers a simple and viable option of HTL modification to realize highly efficient OSCs.
A highly efficient fullerene-free polymer solar cell (PSC) based on PDCBT, a polythiophene derivative substituted with alkoxycarbonyl, achieves an impressive power conversion efficiency of 10.16%, which is the best result in PSCs based on polythiophene derivatives to date. In comparison with a poly(3-hexylthiophene):ITIC-based device, the photovoltaic and morphological properties of the PDCBT:ITIC-based device are carefully investigated and interpreted.
Fullerene-free organic solar cells show over 11% power conversion efficiency, processed by low toxic solvents. The applied donor and acceptor in the bulk heterojunction exhibit almost the same highest occupied molecular orbital level, yet exhibit very efficient charge creation.
Most of the high-performance organic solar cells are fabricated with the assistance of high-boiling-point solvent additives to optimize their charge transport properties; this has adverse effects on the OSCs’ stability and reproducibility in large-scale production. Here, we design volatilizable solid additives by considering the molecular structure feature of an acceptor–donor–acceptor-type non-fullerene acceptor. The application of solid additives can enhance the intermolecular π–π stacking of the non-fullerene acceptor and thus facilitate the charge transport properties in the active layers, leading to improved efficiencies of OSCs. Importantly, devices fabricated using volatilizable solid additives exhibit higher stability and reproducibility when compared with the OSCs processed with solvent additives. Our results not only demonstrate an approach of applying volatilizable solid additives to benefit the large-scale production of OSCs but also provide a potential direction for designing specific solid additives for different active layers.
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