Recently, biocompatible energy harvesting devices have received a great deal of attention for biomedical applications. Among various biomaterials, viruses are expected to be very promising biomaterials for the fabrication of functional devices due to their unique characteristics. While other natural biomaterials have limitations in mass-production, low piezoelectric properties, and surface modification, M13 bacteriophages (phages), which is one type of virus, are likely to overcome these issues with their mass-amplification, self-assembled structure, and genetic modification. Based on these advantages, many researchers have started to develop virus-based energy harvesting devices exhibiting superior properties to previous biomaterial-based devices. To enhance the power of these devices, researchers have tried to modify the surface properties of M13 phages, form biomimetic hierarchical structures, control the dipole alignments, and more. These methods for fabricating virus-based energy harvesting devices can form a powerful strategy to develop high-performance biocompatible energy devices for a wide range of practical applications in the future. In this review, we discuss all these issues in detail.
LaAlO3/SrTiO3 (LAO/STO) heterostructures,
in which a highly mobile two-dimensional electron gas (2DEG) is formed,
have great potential for optoelectronic applications. However, the
inherently high density of the 2DEG hinders the observation of photo-excitation
effects in oxide heterostructures. Herein, a strong photoresponse
of the 2DEG in a Pt/LAO/STO heterostructure is achieved by adopting
a vertical tunneling configuration. The tunneling of the 2DEG through
an ultrathin LAO layer is significantly enhanced by UV light irradiation,
showing a maximum photoresponsivity of ∼1.11 × 107%. The strong and reversible photoresponse is attributed to
the thermionic emission of photoexcited hot electrons from the oxygen-deficient
STO. Notably, the oxygen vacancy defects play a critical role in enhancing
the tunneling photocurrent. Our systematic study on the hysteresis
behavior and the light power dependency of the tunneling current consistently
support the fact that the photoexcited hot electrons from the oxygen
vacancies strongly contribute to the tunneling conduction under the
UV light. This work offers valuable insights into a novel photodetection
mechanism based on the 2DEG as well as into developing ultrathin optoelectronic
devices based on the oxide heterostructures.
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