As-doped ZnO (ZnO:As) films have been characterized. ZnO:As films show p-type characteristics determined by Hall-effect and photoluminescence (PL) measurements. The hole concentration can be increased up to the mid-1017-cm−3 range. The thermal binding energy of the As acceptor (EAth-b) is 120±10 meV, as derived from temperature-dependent Hall-effect measurements. The PL spectra reveal two different acceptor levels (EAopt-b), located at 115 and 164 meV, respectively, above the maximum of the ZnO valence band, and also show the binding energy of the exciton to the As-acceptor (EAXb) is about 12 meV. The values of the ratio EAXb/(EAth-b or EAopt-b) are located in the range from 0.07 to 0.11.

Results are presented for ZnO-based ultraviolet light emitting diodes (LEDs) that employ a BeZnO∕ZnO active layer comprised of seven quantum wells. Arsenic and gallium are used for p-type and n-type layers. The ZnO-based LEDs show two dominant electroluminescence peaks located in the ultraviolet spectral region between 360 and 390nm, as well as a broad peak at 550nm.

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Single-mode quantum cascade lasers employing asymmetric Mach-Zehnder interferometer type cavities Appl. Phys. Lett. 101, 161115 (2012) Bistability patterns and nonlinear switching with very high contrast ratio in a 1550nm quantum dash semiconductor laser Appl. Phys. Lett. 101, 161117 (2012) Relative intensity noise of a quantum well transistor laser Appl. Phys. Lett. 101, 151118 (2012) Blue monolithic AlInN-based vertical cavity surface emitting laser diode on free-standing GaN substrate Appl. Phys. Lett. 101, 151113 (2012) Ground state terahertz quantum cascade lasers

The potential use of ZnO-based photonic and electronic devices has been demonstrated by the fabrication of prototype ultraviolet (UV) photodetector and field-effect transistor (FET) devices that contain films of p-type ZnO with arsenic as the p-type dopant. These p-type films have high crystalline quality and show long-term stability. The ZnO UV photodetectors are based on p-n junctions. The FETs are made with metal-semiconductor Schottky contacts on p-type ZnO and are normally off (enhancement) devices. The spectral and electrical characteristics of these devices are presented and explained.