In this review, we summarize the recent findings on novel narrow-band red phosphors, the improved color and visual energy properties of these phosphors, and their ability to improve the optical properties of corresponding warm white pc-WLED lightings.
In this study, we synthesized and characterized narrow-band red-emitting K 2 SiF 6 :Mn 4+ phosphors in order to improve the color qualities of warm white light-emitting diodes (LEDs). The deep red monochromatic LED was realized through fabricating a long wavelength pass dichroic filter (LPDF)-capped phosphor-converted LED (pc-LED) with a synthesized K 2 SiF 6 :Mn 4+ phosphor. In addition, we introduced four-package white LEDs that combine InGaN blue (B) LED and LPDF-capped green (G), amber (A), and red (R) pc-LEDs to achieve the high color rendition at the warm white correlated color temperatures (CCTs, 2700 K) with the assistance of the narrow-band K 2 SiF 6 :Mn 4+ red phosphor. We compared the optical properties, including the luminous efficacy (LE), luminous efficacy of radiation (LER), color rendering index (CRI), special CRI for strong red (R 9 ), and color quality scale (CQS), of fourpackage white LEDs through varying the red pc-LED with one narrow-band red-emitting phosphor and five wide-band red-emitting phosphors. The RAGB four-package white LED using narrow-band red-emitting K 2 SiF 6 :Mn 4+ phosphor exhibited high LE (107 lm/W) and ultrahigh color qualities (CRI = 94, R 9 = 93, and CQS = 93) at a CCT of 2700 K.
In this study, we report the concerted fabrication process, which is easy to transform the size of active emitting area and produce polarized surface light, using the electric-field-assisted assembly for horizontally assembled many tiny nanorod LEDs between two metal electrodes. We fabricate the millions of individually separated 1D nanorod LEDs from 2D nanorod arrays using nanosphere lithography, etching and cutting process of InGaN/GaN LED structure on a flat sapphire substrate. The horizontally assembled InGaN-based nanorods LED device shows bright (~2,130 cd/m2) and uniform polarized (polarization ratio, ρ = ~0.61) green emissions from large area (0.7 cm × 0.6 cm) planar surface. The realization of a horizontally assembled nanorod LED device can prove the concept of an innovative idea to fabricate formable and scalable polarized surface LED lighting.
We introduce an orientation-controlled alignment process of p-GaN/InGaN multiquantum-well/n-GaN (p/MQW/n InGaN) nanorod light-emitting diodes (LEDs) by applying the direct current (DC) offset-alternating current (AC) or pulsed DC electric fields across interdigitated metal electrodes. The as-forwardly aligned p/MQW/n InGaN nanorod LEDs by a pulsed DC dielectrophoresis (DEP) assembly process improve the electroluminescence (EL) intensities by 1.8 times compared to the conventional AC DEP assembly process under DC electric field operation and exhibit an enhanced applied current and EL brightness in the current-voltage and EL intensity-voltage curves, which can be directly used as the fundamental data to construct DC-operated nanorod LED devices, such as LED areal surface lightings, scalable lightings (micrometers to inches) and formable surface lightings. The enhancement in the applied current, the improved EL intensity, and the increased number of forwardly aligned p/MQW/n InGaN nanorods in panchromatic cathodoluminescence images confirm the considerable enhancement of forwardly aligned one-dimensional nanorod LEDs between two opposite electrodes using DC offset-AC or a pulsed DC electric field DEP assembly process. These DC offset-AC or pulsed DC electric field DEP assembly processes suggest that designing for these types of interactions could yield new ways to control the orientation of asymmetric p/MQW/n InGaN diode-type LED nanorods with a relatively low aspect ratio.
Given that light is known to function as a zeitgeber, having the greatest influence on the human circadian rhythm, it is necessary to assess the effects of light on humans with the goal of maintaining the circadian rhythm. Herein, we fabricated a simple circadian light meter that directly measures the non-visual effects of light using optical filters that mimic the non-visual action spectrum. The fabricated light meter was calibrated and verified through the values obtained from a conventional illuminance spectrophotometer. Furthermore, during 24 h of everyday life, 11 participants wore hats equipped with the developed light meter so that we could investigate the effects of the light environment to which they were exposed to, both indoors and outdoors. For comparison, natural outdoor illumination was also measured with the same light meter. Based on the considerable difference between the light exposure levels during the daytime and nighttime, it is possible that the participant’s melatonin levels would be impacted by the light exposure measured by the light meter. Consequently, based on the light exposure measurements made in this study, the proposed circadian light meter would be a valuable tool for real world circadian lighting studies that require actual light dose to the eyes of the test subjects.
This paper introduces a multi-package light-emitting diode (LED) system with the ability to realize an efficient and good color quality yellow room lamp under a photolithography environment. Various yellow room LEDs were fabricated by combining two, three, and four packages among green (G), yellow (Y), amber (A), and red (R) phosphorconverted LEDs (pc-LEDs) capped with long-wavelength pass dichroic filters (LPDF). The values of luminous efficacy (LE), color rendering index (CRI), and color quality scale (CQS) of the nine combinations of multi-package pc-LEDs are compared and optimized for application to a yellow room lamp. The optical properties of the selected G-A-R multipackage LED are compared with those of fluorescent light tubes (FT) and a yellow fluorescent light tube (YFT), which are generally used in photolithography rooms. The proposed G-A-R multi-package LED provides high luminous efficacy of 100 lm/W and good color quality (CRI of 78 and CQS of 36) at correlated color temperature (CCT) and color coordinates similar to those of currently commercialized YFTs.
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