Fine aggregates significantly affect the drying shrinkage in mortar, but concrete. Limestone sand and blast furnace slag sand can reduce the mortar drying shrinkage. Coarse aggregate characteristics play an important role on the concrete drying shrinkage property. Coarse aggregate strain, specific surface area and pore structure of coarse aggregates are investigated. Total amount of water content parameter on drying shrinkage is introduced.
Pore structural changes in hardened cement pastes, subjected to drying and wetting/drying cycles, were studied at micrometer and nanometer levels. Characterization techniques included Nuclear Magnetic Resonance (NMR), nitrogen and water vapor adsorption, mercury intrusion porosimetry (MIP) and under-water weighing. Coarsening of pore structure was observed with MIP and increase in the true density of C-S-H was suggested by the result of under-water weighing. Decrease in specific surface area due to drying was observed with nitrogen adsorption, and water vapor adsorption associated with Excess Surface Work (ESW) analysis suggested a development of cohesive structure in C-S-H. NMR confirmed polymerization of silicate anion chains. The drying-induced coarsening of pore structure is probably attributed to polymerization of silicate anion chains and development of cohesive structure in C-S-H.
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