High-energy-density battery systems have been critical to applications in consumer electronics, aviation, electric vehicles, and emerging large-scale stationary storage. Here, we report a solid-electrolyte-based liquid Li-S and Li-Se (SELL-S and SELL-Se in short) battery system with the potential to deliver energy density exceeding 500 Wh kg À1 and 1,000 Wh L À1 , together with the ability of low cost and stable electrochemical performance for future concentrated and largescale storage applications.
Water, considered as a universal solvent to dissolve salts, has been extensively studied as liquid electrolyte in electrochemical devices. The water/ice phase transition at around 0 °C presents a common phenomenon in nature, however, the chemical and electrochemical behaviors of ice have rarely been studied. Herein, we discovered that the ice phase provides efficient ionic transport channels and therefore can be applied as generalized solid‐state ionic conductor. Solid state ionic conducting ices (ICIs) of Li+, Na+, Mg2+, Al3+, K+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, and Zn2+, frozen from corresponding sulphate solutions, exhibit ionic conductivities ranging from ≈10−7 S cm−1 (Zn2+) to ≈10−3 S cm−1 (Li+) at temperatures spanning from −20 °C to −5 °C. The discovery of ICIs opens new insight to design and fabrication of solid‐state electrolytes that are simple, inexpensive, and versatile.
Particulate matter (PM) pollution has become a serious problem worldwide and various kinds of nanofibrous filters aiming to solve the problem have been developed. It is urgent to remove PM from high-temperature pollution sources, such as industrial emissions, coal furnaces, and automobile exhaust gases. However, filtration at pollution sources remains challenging because most existing air filters are not resistant to high temperature. Herein, heat-resistant polyimide (PI) nanofibrous air filters are fabricated via a simple and scalable solution blow-spinning method. These air filters show excellent thermal stability at high temperature up to 420 °C. They exhibit a filtration efficiency as high as 99.73% at ambient temperature and over 97% at 300 °C. In addition, a field test shows that the filters remove > 97% of PM from the car exhaust fumes. Hence, the blow-spun PI nanofibrous membranes combined with the facile preparation strategy have great potential in high temperature air filtration fields and other similar applications such as water purification and protein separation.
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