Entropy-engineered materials are garnering considerable attention owing to their excellent mechanical and transport properties, such as their high thermoelectric performance. However, understanding the effect of entropy on thermoelectrics remains a challenge. In this study, we used the PbGeSnCd x Te3+x family as a model system to systematically investigate the impact of entropy engineering on its crystal structure, microstructure evolution, and transport behavior. We observed that PbGeSnTe3 crystallizes in a rhombohedral structure at room temperature with complex domain structures and transforms into a high-temperature cubic structure at ∼373 K. By alloying CdTe with PbGeSnTe3, the increased configurational entropy lowers the phase-transition temperature and stabilizes PbGeSnCd x Te3+x in the cubic structure at room temperature, and the domain structures vanish accordingly. The high-entropy effect results in increased atomic disorder and consequently a low lattice thermal conductivity of 0.76 W m–1 K–1 in the material owing to enhanced phonon scattering. Notably, the increased crystal symmetry is conducive to band convergence, which results in a high-power factor of 22.4 μW cm–1 K–1. As a collective consequence of these factors, a maximum ZT of 1.63 at 875 K and an average ZT of 1.02 in the temperature range of 300–875 K were obtained for PbGeSnCd0.08Te3.08. This study highlights that the high-entropy effect can induce a complex microstructure and band structure evolution in materials, which offers a new route for the search for high-performance thermoelectrics in entropy-engineered materials.
In free-space optical (FSO) communication, high-precision pointing is a critical technology required for rapid acquisition to reduce link establishment time and increase communication time. FSO communication on a motion platform is necessary to expand the communication area and to promote the establishment of a global communication network. However, the pointing accuracy of an optical communication terminal on a motion platform is low due to numerous error sources and error coupling. This paper evaluates the error sources and proposes a pointing model to avoid problems resulting from error coupling. This proposed pointing model was designed to improve the pointing accuracy of a gimbals-type optical communication terminal (GOCT) on a motion platform. The effectiveness of the proposed pointing model was verified by tracking star experiments. The modified residual error of the proposed point model was 94.8 μrad compared to 1324.2 μrad without correction. Additionally, the modified residual error was 94.8 μrad of the proposed pointing model compared to 140.2 μrad of the existing model. The actual open-loop pointing error was reduced from 150.4 μrad of the existing model to 101.3 μrad of the proposed model. Thus, the pointing accuracy of a GOCT on a motion platform was significantly improved after correction by the proposed pointing model.
Intermetallic compounds have attracted considerable attention as advanced structure materials with special properties. While a range of powder metallurgy methods have been developed to synthesize intermetallics, these approaches typically feature slow heating rates and therefore sluggish interdiffusion between the precursor powders, ending up with multiphase products with different metallic ratios. However, single-phase intermetallics offer more controllable properties for materials design yet remain difficult to achieve because of the synthetic limits. Herein, we report a target-sintering approach to synthesize a range of single-phase intermetallics, the stoichiometry of which is simply dictated by the chemical composition of the used precursors without any intermediate phase formation. This unique process is enabled by an ultrafast high-temperature sintering (UHS) method, which crucially offers fast temperature ramping (up to 103–104 °C/min vs. 101–102 °C/min in the conventional methods) to avoid phase impurity, as well as short sintering time to limit elemental loss. As a proof-of-concept demonstration, we synthesized, for the first time, a range of single-phase Ti–Al intermetallics, such as Ti3Al (phase fraction of 99.5%) and TiAl3 (phase fraction of 91.8%). This approach is promising for application to other intermetallic and alloy systems where target-sintering can be used to achieve a variety of single-phase materials.
Reflection fiber temperature sensors functionalized with plasmonic nanocomposite material using intensity-based modulation are demonstrated for the first time. Characteristic temperature optical response of the reflective fiber sensor is experimentally tested using Au-incorporated nanocomposite thin films deposited on the fiber tip, and theoretically validated using a thin-film-optic-based optical waveguide model. By optimizing the Au concentration in a dielectric matrix, Au nanoparticles (NP) exhibit a localized surface plasmon resonance (LSPR) absorption band in a visible wavelength that shows a temperature sensitivity ~0.025%/°C as a result of electron–electron and electron–phonon scattering of Au NP and the surrounding matrix. Detailed optical material properties of the on-fiber sensor film are characterized using scanning electron microscopy (SEM) and focused-ion beam (FIB)-assisted transmission electron microscopy (TEM). Airy’s expression of transmission and reflection using complex optical constants of layered media is used to model the reflective optical waveguide. A low-cost wireless interrogator based on a photodiode transimpedance-amplifier (TIA) circuit with a low-pass filter is designed to integrate with the sensor. The converted analog voltage is wirelessly transmitted via 2.4 GHz Serial Peripheral Interface (SPI) protocols. Feasibility is demonstrated for portable, remotely interrogated next-generation fiber optic temperature sensors with future capability for monitoring additional parameters of interest.
Multi-principal element alloys (MPEA) demonstrate superior synergetic properties compared to single-element predominated traditional alloys. However, the rapid melting and uniform mixing of multi-elements for the fabrication of MPEA structural materials by metallic 3D printing is challenging as it is difficult to achieve both a high temperature and uniform temperature distribution in a sufficient heating source simultaneously. Herein, we report an ultrahigh-temperature melt printing method that can achieve rapid multi-elemental melting and uniform mixing for MPEA fabrication. In a typical fabrication process, multi-elemental metal powders are loaded into a high-temperature column zone that can be heated up to 3000 K via Joule heating, followed by melting on the order of milliseconds and mixing into homogenous alloys, which we attribute to the sufficiently uniform high-temperature heating zone. As proof-of-concept, we successfully fabricated single-phase bulk NiFeCrCo MPEA with uniform grain size. This ultrahigh-temperature rapid melt printing process provides excellent potential toward MPEA 3D printing.
Metastable alloys with transformation-/twinning-induced plasticity (TRIP/TWIP) can overcome the strength-ductility trade-off in structural materials. Originated from the development of traditional alloys, the intrinsic stacking fault energy (ISFE) has been applied to tailor TRIP/TWIP in high-entropy alloys (HEAs) but with limited quantitative success. Here, we demonstrate a strategy for designing metastable HEAs and validate its effectiveness by discovering seven alloys with experimentally observed metastability for TRIP/TWIP. We propose unstable fault energies as the more effective design metric and attribute the deformation mechanism of metastable face-centered cubic alloys to unstable martensite fault energy (UMFE)/unstable twin fault energy (UTFE) rather than ISFE. Among the studied HEAs and steels, the traditional ISFE criterion fails in more than half of the cases, while the UMFE/UTFE criterion accurately predicts the deformation mechanisms in all cases. The UMFE/UTFE criterion provides an effective paradigm for developing metastable alloys with TRIP/TWIP for an enhanced strength-ductility synergy.
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