With
the development of advanced electronic devices and electric
power systems, polymer-based dielectric film capacitors with high
energy storage capability have become particularly important. Compared
with polymer nanocomposites with widespread attention, all-organic
polymers are fundamental and have been proven to be more effective
choices in the process of scalable, continuous, and large-scale industrial
production, leading to many dielectric and energy storage applications.
In the past decade, efforts have intensified in this field with great
progress in newly discovered dielectric polymers, fundamental production
technologies, and extension toward emerging computational strategies.
This review summarizes the recent progress in the field of energy
storage based on conventional as well as heat-resistant all-organic
polymer materials with the focus on strategies to enhance the dielectric
properties and energy storage performances. The key parameters of
all-organic polymers, such as dielectric constant, dielectric loss,
breakdown strength, energy density, and charge–discharge efficiency,
have been thoroughly studied. In addition, the applications of computer-aided
calculation including density functional theory, machine learning,
and materials genome in rational design and performance prediction
of polymer dielectrics are reviewed in detail. Based on a comprehensive
understanding of recent developments, guidelines and prospects for
the future development of all-organic polymer materials with dielectric
and energy storage applications are proposed.
Recently, sensors that can imitate human skin have received extensive attention. Capacitive sensors have a simple structure, low loss, no temperature drift, and other excellent properties, and can be applied in the fields of robotics, human-machine interactions, medical care, and health monitoring. Polymer matrices are commonly employed in flexible capacitive sensors because of their high flexibility. However, their volume is almost unchanged when pressure is applied, and they are inherently viscoelastic. These shortcomings severely lead to high hysteresis and limit the improvement in sensitivity. Therefore, considerable efforts have been applied to improve the sensing performance by designing different microstructures of materials. Herein, two types of sensors based on the applied forces are discussed, including pressure sensors and strain sensors. Currently, five types of microstructures are commonly used in pressure sensors, while four are used in strain sensors. The advantages, disadvantages, and practical values of the different structures are systematically elaborated. Finally, future perspectives of microstructures for capacitive sensors are discussed, with the aim of providing a guide for designing advanced flexible and stretchable capacitive sensors via ingenious human-made microstructures.
Dielectric elastomer actuators (DEAs) with large electrically-actuated strain can build light-weight and flexible non-magnetic motors. However, dielectric elastomers commonly used in the field of soft actuation suffer from high stiffness, low strength, and high driving field, severely limiting the DEA’s actuating performance. Here we design a new polyacrylate dielectric elastomer with optimized crosslinking network by rationally employing the difunctional macromolecular crosslinking agent. The proposed elastomer simultaneously possesses desirable modulus (~0.073 MPa), high toughness (elongation ~2400%), low mechanical loss (tan δm = 0.21@1 Hz, 20 °C), and satisfactory dielectric properties ($${\varepsilon }_{{{{{{\rm{r}}}}}}}$$
ε
r
= 5.75, tan δe = 0.0019 @1 kHz), and accordingly, large actuation strain (118% @ 70 MV m−1), high energy density (0.24 MJ m−3 @ 70 MV m−1), and rapid response (bandwidth above 100 Hz). Compared with VHBTM 4910, the non-magnetic motor made of our elastomer presents 15 times higher rotation speed. These findings offer a strategy to fabricate high-performance dielectric elastomers for soft actuators.
Polymer dielectrics for energy storage applications usually endure high electric field strength. Adjustment of the composition and structure of dielectric bulk phase to enhance the dielectric breakdown strength has been...
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