A new analytical method, combining the hollow fiber membrane, cryofocusing, and thermal desorption technologies, has been developed to allow rapid routine analysis and long-term continuous monitoring of volatile organic compounds in various environmental matrices. This method of membrane extraction with a sorbent interface (MESI) is simple, effective, and solventfree and easy to automate. It minimizes the loss of analytes
This paper presents the theory and experimental implementation of the technique of membrane extraction with a sorbent interface for air analysis. A mathematical model was derived to predict the extraction process and the significant factors, such as membrane length and carrier gas flow rate. A benzene/nitrogen standard gas mixture was generated by the permeation tube method. Several
A cap-shaped device was employed for headspace sampling. This sampling device coupled to membrane extraction with a sorbent interface (MESI) is intended to perform on-site and on-line aqueous sample monitoring. A laboratory sampling testwas performed both at the water surface and under water, and it showed some advantages in underwater monitoring. A group of volatile organic compounds (VOCs), varying in PDMS/gas and gas/water distribution constants, benzene, toluene, ethylbenzene, o-xylene, and trichloroethylene (TCE), was used for the sampling study. Magnetic stirring of the sample and circulation of the headspace air with a microfan were used for the enhancement of mass transfer between sample matrix and membrane to obtain higher extraction rate and efficiency. The agitation approaches were investigated individually and compared. The results showed that simultaneous agitation in water and air could greatly improve the extraction efficiency. Good linearity and precision and low detection limits were obtained for water-surface monitoring. The study demonstrated that Cap-MESI is a useful tool for field headspace monitoring of volatile organic compounds.
Calibration methods based on the recently developed mathematical model are proposed for air monitoring by membrane extraction. In membrane extraction, analytes permeate through the membrane at a constant rate controlled by the distribution constant and the diffusion coefficient. The principle of the proposed calibration approach is based on either theoretical or experimental determination of both constants at the extraction conditions. A group of selected compounds was employed for the experimental testing, and the results indicated practical feasibility of the approach. On-line determination of partition coefficients and distribution constants was proposed and investigated, producing very promising results. Both approaches to calibration facilitate quantitative monitoring.
In this paper, a novel method with good numerical stability is proposed from the perspective of energy preserving to alleviate the numerical dissipations in the advection step of Eulerian fluid simulation. The main idea is to measure the vorticity loss during advection, calculate the lost angular kinetic energy with a proposed scheme, and then synthesize a high-frequency incompressible details field to compensate the lost energy in a way that is consistent with Kolmogorov's theory, which prevents the synthetic details from interfering with the existing fluid flow. The method works independently of the advection scheme and can be easily combined with other advection schemes to enhance the effect. It adds only 5% to 10% of the computational overhead while producing convincing fluid details without changing the overall behavior of the original flow.
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