Methodology of using megavolt electrons for investigation of the functionality of thin polymer films of polycyanurates (PCN) is described. The relevance of research is determined by the prospects of using films as a functional basis for improvement of track-etched technologies of nanoporous nuclear filters, where ionizing radiation is used in most of technological stages of their production. Functionality control is the main criterion for the qualification of films on the suitability for production of nuclear filters on their base. Development of megavolt electrons radiation methods is promising for monitoring the functionality of filters. Radiation technologies are universal and able to provide maximum information content on investigations of the characteristics of materials to qualify them for suitability of practical use. To control the functionality of the films, the methodology for research and testing of thin polymer films using powerful electron beams of 1-2 MeV has been developed. The features of these methods and the results of their application at the control of functionality and for the qualification of the films based on crosslinked polycyanurates, synthesized by in situ polycyclotrimerization of dicyanate ester of bisphenol E in the presence of dimethylphthalate (DMPh) of the composition PCN/DMPh=70/30 wt.%, on the suitability for production of nanoporous track membranes are discussed. Key words: electron beams, nuclear membranes, thermostable polycyanurates, radiation stability, functional testing.
The results of implementing equipment qualification are analyzed. Such equipment is critical for the nuclear and technical safety of domestic nuclear power plants that are especially important for the implementation of the Program for extending the terms of out-of-project operation of power reactors that are capable of being used as powerful sources of electricity. Based on the comparison of published reliability indicators of domestic nuclear power plants before and after implementing the qualification, it is shown that still there are problems to be solved. The perspective of further enhancing the reliability of the operation of domestic nuclear energetics is considered, by implementing radiation functional testing methods that are been developed at the INR NAS of Ukraine for a long period. The basis of this method is detailed research and operational control of all processes that occur in critical equipment in any operating modes of nuclear reactors to form a resource history of the equipment and to provide operational information about the remaining resource and the expected time of its failure to an on-line object operator.
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