In this work, the cocoa pod husk (CPH) was converted into biochar products at higher carbonization temperatures (i.e., 400–800 °C). The pore and chemical properties of the resulting biochars and its post-leaching biochars by acid washing, including specific surface area, total pore volume, pore size distribution, true density, and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) and Fourier Transform infrared spectroscopy (FTIR) were studied. Based on the pore properties, pyrolysis temperature at around 800 °C seemed to have the most profound impact on the pore development for producing biochar, where its Brunauer–Emmet–Teller (BET) surface area is 101 m2/g. More noticeably, more pores in the CPH-based biochar could be significantly created during the acid-washing, resulting in an increase of BET surface area from 101 to 342 m2/g. According to the data on the EDS and FTIR, the resulting biochars seemed to have oxygen-containing functional groups on the surface. Furthermore, the methylene blue (MB) adsorption performance of the optimal biochar product with maximal BET surface area was tested to fit its kinetics by the pseudo-second order model, showing a strong interaction between the biochar adsorbent and the cationic adsorbate.
In this work, cow manure (CM) was reused as a potential precursor in the production of activated carbon (AC) using a potassium hydroxide activation process at different temperatures (i.e., 500, 600 and 700 °C). The optimal activated carbon from cow manure (CM-AC) with high specific surface area (ca. 950 m2/g) was further investigated for its adsorption performance in the removal of a model compound (i.e., methylene blue) from aqueous solution with various initial concentrations and adsorbent dosages at 25 °C. It was found that the resulting AC could be an effective adsorbent for removal of cationic dye from aqueous solution in comparison with a commercial coal-based AC. Based on the observations of the energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy (FTIR), the CM-AC adsorbent has a stronger interaction with the cationic compound due to its more oxygen-containing complex on the surface. Furthermore, the adsorption kinetic parameters fitted using the pseudo-second order model with high correlations were in accordance with their pore properties.
In this work, the thermochemical analyses of dairy manure (DM), including the proximate analysis, ultimate (elemental) analysis, calorific value, thermogravimetric analysis (TGA), and inorganic elements, were studied to evaluate its potential for producing DM-based char (DMC) with high porosity. The results showed that the biomass should be an available precursor for producing biochar materials based on its high contents of carbon (42.63%) and volatile matter (79.55%). In order to characterize their pore properties, the DMC products produced at high pyrolysis temperatures (500–900°C) were analyzed using surface area and porosity analyzer, pycnometer, and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS). The values of pore properties for the DMC products increased with an increase in pyrolysis temperature, leading to more pore development and condensed aromatic cluster at elevated temperatures. Because of the microporous and mesoporous structures from the N2 adsorption–desorption isotherms with the hysteresis loops (H4 type), the Brunauer–Emmett–Teller (BET) surface area of the optimal biochar (DMC-900) was about 360 m2/g, which was higher than the data reported in the literature. The highly porous structure was also seen from the SEM observations. More significantly, the cation exchange capacity (CEC) of the optimal DMC product showed a high value of 57.5 ± 16.1 cmol/kg. Based on the excellent pore and chemical properties, the DMC product could be used as an effective amendment and/or adsorbent for the removal of pollutants from the soil media and/or fluid streams.
The use of biochar in the horticulture and crop fields is a recent method to improve soil fertility due to its porous features and rich nutrients. In the present study, dairy manure (DM) was used as a biomass precursor in the preparation of highly porous biochar (DM-BC) produced at specific conditions. Based on N2 adsorption-desorption isotherms and scanning electron microscopy (SEM) observations, the resulting biochar featured its microporous/mesoporous textures with a BET surface area of about 300 m2/g and total pore volume of 0.185 cm3/g, which could be a low-cost biosorbent for the effective removal of methylene blue (MB) from the aqueous solution. As observed by the energy dispersive X-ray spectroscopy (EDS), the primary inorganic nutrients on the surface of DM-BC included calcium (Ca), magnesium (Mg), potassium (K), phosphorus (P), silicon (Si), sulfur (S), sodium (Na) and aluminum (Al). Furthermore, the resulting biochar was investigated in duplicate for its biosorption performance of cationic compound (i.e., methylene blue, MB) from the aqueous solution with various initial MB concentrations and DM-BC dosages at 25 °C. The findings showed that the biosorption kinetic parameters fitted by the pseudo-second order rate model with high correlations were consistent with its porous features. These experimental results suggested that the porous DM-based biochar could be reused as a biosorbent, biofertilizer, or soil amendments due to the high porosity and the abundance in nutrient minerals.
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