Wood–plastic composite (WPC) material has been developed rapidly and used widely to replace wood production in recent years. The cutting process of WPC material is the key to directly affect the efficiency of utilization and processing. The infrared thermal imaging system and numerical control machine tool were used in this article to analyze the cutting temperature under different cutting parameters, which was further compared with massoniana wood cutting procedure to provide theoretical basis for WPC material processing. Under certain conditions, the cutting depth was the most important factor on the cutting temperature, followed by spindle speed, while cutting width was the least affected. In the cases of similar processing parameters, although cutting temperature for massoniana wood is always higher than WPCs, the change trends of their cutting temperature are similar. Besides, shear heat moderately affected the cutting temperature during cutting.
Polyethylene glycol acrylate-grfat-Cellulose-acrylate (PEGA-g-CEA) has been synthesized as side-chain-type solid-solid phase change materials for thermal energy storange through graft copolymerization. The composition and structure of the grafts and cellulose, phase transition properties and morphology of grafts were investigated by Fourier transform infrared spectrometer (FTIR), differential scaanning calorimentry (DSC) and optical microscopy. The results show that the polyethylene glycol (PEG) successfully grafted onto the cellulose macromolecule, and the solid-solid phase change materials with a certain phase transformation ability were obtained through this experiment.
The novel form-stable composite phase change materials (PCMs) of crosslinked PEGA and P(PEGA-HAM)/PEG gels were synthesized, which based on PEGA . Using crosslinked PEGA and P(PEGA-HAM)/PEG gels as the working substance , PP/PCM thermo-regulating fibers were prepared by blends via melt spinning respectively. TGA results indicate that the crosslinked form-stable PCMs have good thermal stability. The morphology of the surface of PP/PCM thermo-regulating fibers smooth mainly by SEM. The breaking strength of thermo-regulating fibers first increases and then decreases when increased some content of PCM. DSC results indicate the phase enthalpy of PEGA crosslinked gel and its the blend fibers with PP are 122.97J/g and 13.83J/g, while that of P(PEGA-HAM)/PEG crosslinked networks gel and its the blend fibers with PP are 107.48J/g and 4.62J/g respectively.
Regioregular head-tail poly(3-hexylthiophenes) (HT-P3HT) with a controlled high molecular weight and a small polydispersity have been synthesized via an improved Kumada catalyst-transfer polycondensation (KCTP) by using the new-prepared hexylmagnesium bromide as the Grignard reagent. As the amount of nickel catalyst dichloro[1,3-diphenylphosphinopropane] nickel (Ni(dppp)Cl2) was 0.5% mol of the amount of monomer 2,5-dibromo-3-hexylthiophene (DBHT) we can obtain a HT-P3HT with a high molecular weight Mn (38 449) and a small polydspersity (1.18). By using of LiCl as a co-catalyst, the regioregularity of the P3HT with high molecular weight (40 270) is maintained and the PDI (1.03) is smaller than that of the P3HT polymerized in the absence of LiCl but the conversion ratio of the monomer is promoted. The HT-P3HT with high molecular weight and small polydispersity will be an attractive candidate applied in solar cells.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.