Ni3Te2 has been reported as a highly efficient OER electrocatalyst with an overpotential of 180 mV at 10 mA cm−2 and also showing HER catalytic activity in alkaline medium.
Crystalline–amorphous phase boundary engineering can be an effective strategy to develop cost-effective and high-performance electrocatalysts for water splitting.
The rational design of multifunctional catalysts that use non-noble metals to facilitate the interconversion between H2, O2, and H2O is an intense area of investigation. Bimetallic nanosystems with highly tunable electronic, structural, and catalytic properties that depend on their composition, structure, and size have attracted considerable attention. Herein, we report the synthesis of bimetallic nickel–copper (NiCu) alloy nanoparticles confined in a sp2 carbon framework that exhibits trifunctional catalytic properties toward hydrogen evolution (HER), oxygen reduction (ORR), and oxygen evolution (OER) reactions. The electrocatalytic functions of the NiCu nanoalloys were experimentally and theoretically correlated with the composition-dependent local structural distortion of the bimetallic lattice at the nanoparticle surfaces. Our study demonstrated a downshift of the d-band of the catalysts that adjusts the binding energies of the intermediate catalytic species. XPS analysis revealed that the binding energy for Ni 2p3/2 band of the Ni0.25Cu0.75/C nanoparticles was shifted ∼3 times compared to other bimetallic systems, and this was correlated to the high electrocatalytic activity observed. Interestingly, the bimetallic Ni0.25Cu0.75/C catalyst surpassed the OER performance of RuO2 benchmark catalyst exhibiting a small onset potential of 1.44 V vs RHE and an overpotential of 400 mV at 10 mA·cm–2 as well as the electrochemical long-term stability of commercial RuO2 and Pt catalysts and kept at least 90% of the initial current applied after 20 000 s for the OER/ORR/HER reactions. This study reveals significant insight about the structure–function relationship for non-noble bimetallic nanostructures with multifunctional electrocatalytic properties.
The electrocatalytic performance of transition metal sulfide (TMS)− graphene composites has been simply regarded as the results of high conductivity and the large surface/volume ratio. However, unavoidable factors such as degree of oxidation of TMSs have been hardly considered for the origin of this catalytic activity of TMS−graphene composites. To accomplish the reliable application of TMS-based electrocatalytic materials, a clear understanding of the thermodynamic stability of TMS and effects of oxidation on catalytic activity is necessary. In addition, the mechanism of charge transfer at the TMS−graphene interface must be studied in depth to properly design composite materials. Herein, we report a comprehensive study of the physical chemistry at the junction of a Co 1−x Ni x S 2 −graphene composite, which is a prototype designed to unravel the mechanisms of charge transfer between TMS and graphene. Specifically, the thermodynamic stability and the effects of oxidation of TMSs during the oxygen evolution reaction (OER) on the reaction mechanism are systematically investigated using density functional theory (DFT) calculations and experimental observations. Cobalt atoms anchored on pyridinic N sites in the graphene support form metal−semiconductor (SC) junctions, and the internal band bending at these junctions facilitates electron transfer from TMSs to graphene. The junction enables fast sinking of the excess electron from OH − adsorbate. Partially oxidized amorphous TMS layers formed during the OER can facilitate adsorption and desorption of OH and H atoms, boosting the OER performance of TMS−graphene nanocomposites. From the DFT calculations, the enhanced electrocatalytic activity of TMS−graphene nanocomposites originates from two important factors: (i) increased internal band bending and (ii) parallelized OER pathways at the interface of pristine and oxidized TMSs.
Focused ultrasound combined with bubble-based agents serves as a non-invasive way to open the blood-brain barrier (BBB). Passive acoustic detection was well studied recently to monitor the acoustic emissions induced by the bubbles under ultrasound energy, but the ability to perform reliable BBB opening with a real-time feedback control algorithm has not been fully evaluated. This study focuses on characterizing the acoustic emissions of different types of bubbles: Optison, Definity, and a custom-made nanobubble. Their performance on reliable BBB opening under real-time feedback control based on acoustic detection was evaluated both in-vitro and in-vivo. The experiments were conducted using a 0.5 MHz focused ultrasound transducer with in-vivo focal pressure ranges from 0.1–0.7 MPa. Successful feedback control was achieved with all three agents when combining with infusion injection. Localized opening was confirmed with Evans blue dye leakage. Microscopic images were acquired to review the opening effects. Under similar total gas volume, nanobubble showed a more reliable opening effect compared to Optison and Definity (p < 0.05). The conclusions obtained from this study confirm the possibilities of performing stable opening using a feedback control algorithm combined with infusion injection. It also opens another potential research area of BBB opening using sub-micron bubbles.
Designing high-efficiency electrocatalysts for water oxidation has become an increasingly important concept in the catalysis community due to its implications in clean energy generation and storage. In this respect transition-metal-doped mixed-metal selenides incorporating earth-abundant elements such as Ni and Fe have attracted attention due to their unexpectedly high electrocatalytic activity toward the oxygen evolution reaction (OER) with low overpotential in alkaline medium. In this article, quaternary mixed-metal selenide compositions incorporating Ni-Fe-Co were investigated through combinatorial electrodeposition by exploring the ternary phase diagram of Ni-Fe-Co systems. The OER electrocatalytic activity of the resultant quaternary and ternary mixed-metal selenide compositions was measured in order to systematically investigate the trend of catalytic activity as a function of catalyst composition. Accordingly, the composition(s) exhibiting the best catalytic efficiency for the quaternary Fe-Co-Ni mixed-metal selenide was identified. It was observed that the quaternary selenide outperformed the binary as well as the ternary metal selenides in this Ni-Fe-Co phase space. The elemental composition and relative abundance of the elements in the catalyst film was ascertained from energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). Mapping of the OER catalytic activity as a function of catalyst composition indicated that catalytic efficiency was more pronounced in the Fe-rich region with moderate amounts of Ni and trace amounts of Co doping, and the best performance was exhibited by (Ni0.25Fe0.68Co0.07)3Se4, which showed an overpotential of 230 mV (vs RHE) at 10 mA cm–2 with stability exceeding 8 h for continuous oxygen generation. It was also observed that typically the quaternary metal selenide composition was close to AB2Se4, which shows a spinel structure type. Electrochemical measurements along with density functional theory (DFT) calculations were performed to correlate the enhancement of catalytic activity toward the Fe-rich region with composition. First-principles DFT calculations were used to estimate the hydroxyl adsorption energy (E ads) on the surface of the mixed-metal selenides with varying compositions. This adsorption energy could be directly correlated to the onset of OER activity, and the results matched very well with the experimentally observed trend with respect to onset overpotential. The knowledge of the trend of catalytic activity as a function of composition will be very important for catalyst design through targeted material synthesis. This work represents an example of a systematic phase exploration for quaternary metal selenides and provides a strong foundation which can be expanded to study other mixed-metal selenide combinations.
Metal–metalloid compounds have been paid much attention as new high‐performance water oxidation catalysts due to their exceptional durability for water oxidation in alkaline media originating from the multi‐dimensional covalent bonding of the metalloid with the surrounding metal atoms. However, compared to the excellent stability, a relatively low catalytic activity of metal‐metalloids often limits their practical application as high‐performance water oxidation catalysts. Here, for the first time, disclosed is a novel self‐templating strategy combined with atomic layer deposition (ALD) to design the electrochemically active and stable quaternary metal boride (vanadium‐doped cobalt nickel boride, VCNB), hollow nanoprism by inducing electronic double layers on the surface. The incorporation of V in a double‐layered structure can substantially increase the number of surface active sites with unsaturated electronic structure. Furthermore, the induced electronic double layers of V can effectively protect the dissolution of the surface active sites. In addition, density functional theory (DFT) calculations reveal that the impressive water oxidation properties of VCNB originate from the synergetic physicochemical effects of the different metal elements, Co and B as active sites, Ni as a surface electronic structure modifier, and V as a charge carrier transporter and supplier.
The wood cell wall features a tough and relatively rigid fiber reinforced composite structure. It acts as a pressure vessel, offering protection against mechanical stress. Cellulose microfibrils, hemicellulose and amorphous lignin are the three major components of wood. The structure of secondary cell wall could be imagined as the same as reinforced concrete, in which cellulose microfibrils acts as reinforcing steel bar and hemicellulose-lignin matrices act as the concrete. Therefore, the interface between cellulose and hemicellulose/lignin plays a significant role in determine the mechanical behavior of wood secondary cell wall. To this end, we present a molecular dynamics (MD) simulation study attempting to quantify the strength of the interface between cellulose microfibrils and hemicellulose. Since hemicellulose binds with adjacent cellulose microfibrils in various patterns, the atomistic models of hemicellulose-cellulose composites with three typical binding modes, i.e. bridge, loop and random binding modes are constructed. The effect of the shape of hemicellulose chain on the strength of hemicellulose-cellulose composites under shear loadings is investigated. The contact area as well as hydrogen bonds between cellulose and hemicellulose, together with the covalent bonds in backbone of hemicellulose chain are found to be the controlling parameters which determine the strength of the interfaces in the composite system. For the bridge binding model, the effect of shear loading direction on the strength of the cellulose material is also studied. The obtained results suggest that the shear strength of wood-inspired engineering composites can be optimized through maximizing the formations of the contributing hydrogen bonds between cellulose and hemicellulose.
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