Terahertz (THz) shielding becomes increasingly important with the growing development of THz electronics and devices. Primarily materials based on carbon nanostructures or polymer–carbon nanocomposites have been explored for this application. Herein, significantly enhanced THz shielding efficiencies for 2D titanium carbide (Ti3C2 MXene) thin films with nanoscale THz metamaterials are presented. Nanoscale slot antenna arrays with strong resonances at certain frequencies enhance THz electromagnetic waves up to three orders of magnitude in transmission, which in turn enormously increases the shielding performance in combination with MXene films. Drop‐casting of a colloidal solution of MXene (a few micrograms of dry material) can produce an ultrathin film (several tens of nanometers in thickness) on a slot antenna array. Consequently, THz waves strongly localized in the near‐field regime by the slot antenna undergo enhanced absorption through the film with a magnified effective refractive index. Finally, the combination of an ultrathin MXene film and a nano‐metamaterial shows excellent shielding performance in the THz range.

We experimentally demonstrate the use of a bulk-structured Bi(2)Te(3) topological insulator (TI) as an ultrafast mode-locker to generate femtosecond pulses from an all-fiberized cavity. Using a saturable absorber based on a mechanically exfoliated layer about 15 μm thick deposited onto a side-polished fiber, we show that stable soliton pulses with a temporal width of ~600 fs can readily be produced at 1547 nm from an erbium fiber ring cavity. Unlike previous TI-based mode-locked laser demonstrations, in which high-quality nanosheet-based TIs were used for saturable absorption, we chose to use a bulk-structured Bi(2)Te(3) layer because it is easy to fabricate. We found that the bulk-structured Bi(2)Te(3) layer can readily provide sufficient nonlinear saturable absorption for femtosecond mode-locking even if its modulation depth of ~15.7% is much lower than previously demonstrated nanosheet-structured TI-based saturable absorbers. This experimental demonstration indicates that high-crystalline-quality atomic-layered films of TI, which demand complicated and expensive material processing facilities, are not essential for ultrafast laser mode-locking applications.

Tungsten ditelluride (WTe2) is a layered material that exhibits excellent magnetoresistance and thermoelectric behaviors, which are deeply related with its distorted orthorhombic phase that may critically affect the lattice dynamics of this material. Here, we report comprehensive characterization of Raman spectra of WTe2 from bulk to monolayer using experimental and computational methods. We find that mono and bi-layer WTe2 are easily identified by Raman spectroscopy since two or one Raman modes that are observed in higher-layer WTe2 are greatly suppressed below the noise level in the mono- and bi-layer WTe2, respectively. In addition, the frequency of in-plane A1(7) mode of WTe2 remains almost constant as the layer number decreases, while all the other Raman modes consistently blueshift, which is completely different from the vibrational behavior of hexagonal metal dichalcogenides. First-principles calculation validates experimental results and reveals that anomalous lattice vibrations in WTe2 are attributed to the formation of tungsten chains that make WTe2 structurally one-dimensional.

We demonstrate the use of an all-fiberized, mode-locked 1.94 μm laser with a saturable absorption device based on a tungsten disulfide (WS2)-deposited side-polished fiber. The WS2 particles were prepared via liquid phase exfoliation (LPE) without centrifugation. A series of measurements including Raman spectroscopy, scanning electron microscopy (SEM), and atomic force microscopy (AFM) revealed that the prepared particles had thick nanostructures of more than 5 layers. The prepared saturable absorption device used the evanescent field interaction mechanism between the oscillating beam and WS2 particles and its modulation depth was measured to be ~10.9% at a wavelength of 1925 nm. Incorporating the WS2-based saturable absorption device into a thulium-holmium co-doped fiber ring cavity, stable mode-locked pulses with a temporal width of ~1.3 ps at a repetition rate of 34.8 MHz were readily obtained at a wavelength of 1941 nm. The results of this experiment confirm that WS2 can be used as an effective broadband saturable absorption material that is suitable to passively generate pulses at 2 μm wavelengths.

We experimentally demonstrate the use of a bulk-like, MoSe₂-based saturable absorber (SA) as a passive harmonic mode-locker for the production of femtosecond pulses from a fiber laser at a repetition rate of 3.27 GHz. By incorporating a bulk-like, MoSe₂/PVA-composite-deposited side-polished fiber as an SA within an erbium-doped-fiber-ring cavity, mode-locked pulses with a temporal width of 737 fs to 798 fs can be readily obtained at various harmonic frequencies. The fundamental resonance frequency and the maximum harmonic-resonance frequency are 15.38 MHz and 3.27 GHz (212th harmonic), respectively. The temporal and spectral characteristics of the output pulses are systematically investigated as a function of the pump power. The output pulses exhibited Gaussian-temporal shapes irrespective of the harmonic order, and even when their spectra possessed hyperbolic-secant shapes. The saturable absorption and harmonic-mode-locking performance of our prepared SA are compared with those of previously demonstrated SAs that are based on other transition metal dichalcogenides (TMDs). To the best of the authors' knowledge, the repetition rate of 3.27 GHz is the highest frequency that has ever been demonstrated regarding the production of femtosecond pulses from a fiber laser that is based on SA-induced passive harmonic mode-locking.

2D transition metal carbides, nitrides, and carbonitrides called MXenes have attracted increasing attention due to their outstanding properties in many fields. By performing systematic density functional theory calculations, here we show that MXenes can serve as excellent terahertz detecting materials. Giant optical absorption and extinction coefficients are observed in the terahertz range in the most popular MXene, namely, TiC, which is regardless of the stacking degree. Various other optical properties have been investigated as well in the terahertz range for in-depth understanding of its optical response. We find that the thermoelectric figure of merit (ZT) of stacked TiC flakes is comparable to that of carbon nanotube films. Based on excellent terahertz absorption and decent thermoelectric efficiency in MXenes, we finally suggest the promise of MXenes in terahertz detection applications, which includes terahertz bolometers and photothermoelectric detectors. Possible ZT improvements are discussed in large-scale MXene flake films and/or MXene-polymer composite films.

Nanoscale sensors based on single-walled carbon nanotube (SWNT) networks have been considered impractical due to several fundamental limitations such as a poor sensitivity and small signal-to-noise ratio. Herein, we present a strategy to overcome these fundamental problems and build highly-sensitive low-noise nanoscale sensors simply by controlling the structure of the SWNT networks. In this strategy, we prepared nanoscale width channels based on aligned SWNT networks using a directed assembly strategy. Significantly, the aligned network-based sensors with narrower channels exhibited even better signal-to-noise ratio than those with wider channels, which is opposite to conventional random network-based sensors. As a proof of concept, we demonstrated 100 nm scale low-noise sensors to detect mercury ions with the detection limit of approximately 1 pM, which is superior to any state-of-the-art portable detection system and is below the allowable limit of mercury ions in drinking water set by most government environmental protection agencies. This is the first demonstration of 100 nm scale low-noise sensors based on SWNT networks. Considering the increased interests in high-density sensor arrays for healthcare and environmental protection, our strategy should have a significant impact on various industrial applications.

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