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As a stacked form of ultrathin polymer films, multilayer nanostructures are of great interest in various applications. Coarse-grained molecular dynamics simulations were carried out to understand the behaviors of interfacial diffusion and bonding of multilayer polymer films. We found two obvious stages for the interfacial diffusion of polymers in the multilayer film, and it is 3 times faster in the first stage than in the second one due to the evolution of molecular conformations. The polymers near the interfaces have an in-plane mobility much higher than the out-of-plane one. The strength of interfacial bonding has been characterized by the fast tensile stress-strain curve along the normal direction. It shows multiple yielding points for the multilayer polymer films, which is distinct from the tensile behavior of the bulk. The ultimate tensile stress (UTS) and corresponding separating strain, surprisingly, do not necessarily increase with diffusion time. Because of the dramatic molecular rotation and extension during the first stage of interfacial diffusion, the interlayer interpenetration is nonuniformly distributed in the plane of the interface. Such a nonuniform distribution may be one of the reasons for the decrease of the UTS and separating strain.

Cell structure is a key factor that determines the final properties of microcellular polylactide (PLA) product. In the mold opening process, adjusting the rate of mold opening can effectively control cell structure. PLA and PLA composites with a void fraction as high as 50% were fabricated using the mold opening technique. The effects of mold opening rate and the addition of nanoclay on the cell structure, mechanical properties, and surface quality of microcellular PLA and PLA composites samples were investigated. The results showed that finer cell structure was received in the microcellular PLA samples and the surface quality was improved effectively when decreasing the rate of mold opening. The effect of mold opening rate on the foaming behavior of microcellular PLA-nanoclay was the same as that of microcellular PLA. The addition of 5 wt % nanoclay significantly improved the foaming properties, such as cell density, cell size, and structural uniformity, which consequently enhanced the mechanical properties of foams and the surface quality.

Magnetic nanofibers (MNFs) are integrated with a variety of properties, such as large surface area, high porosity, small size effect and apparent magnetism. This enables MNFs to possess excellent properties of both nanofibers (NFs) and magnetic materials, which greatly widens the application of the original magnetic materials. A brief review of the properties of MNFs, fabrication techniques, and their emerging applications which include biomedical application, sensing and electronic devices, wastewater treatment and microwave absorption is presented. Finally, the development trend and prospect of MNFs in future are summarized and discussed.