To date, magnetic proximity effect (MPE) has only been conclusively observed in ferromagnet (FM) based systems. We report the observation of anomalous Hall effect and anisotropic magnetoresistance in angular dependent magnetoresistance (ADMR) measurements in Pt on antiferromagnetic (AF) α-Fe2O3(0001) epitaxial films at 10 K, which provide evidence for the MPE. The Néel order of α-Fe2O3 and the induced magnetization in Pt show a unique ADMR compared with all other FM and AF systems. A macrospin response model is established and can explain the AF spin configuration and all main ADMR features in the Pt/α-Fe2O3 bilayers.
Transition
metal phosphorus trisulfide materials have received
considerable research interest since the 1980–1990s as they
exhibit promising energy conversion and storage properties. However,
the mechanistic insights into Li-ion storage in these materials are
poorly understood to date. Here, we explore the lithiation of NiPS3 material by employing in situ pair-distribution
function analysis, Monte Carlo molecular dynamics calculations, and
a series of ex situ characterizations. Our findings
elucidate complex ion insertion and storage dynamics around a layered
polyanionic compound, which undergoes intercalation and conversion
reactions in a sequential manner. This study of NiPS3 material
exemplifies the Li-ion storage mechanism in transition metal phosphorus
sulfide materials and provides insights into the challenges associated
with achieving reliable, high-energy phosphorus trisulfide systems.
Catastrophic accidents caused by fatigue failures often occur in engineering structures. Thus, a fundamental understanding of cyclic-deformation and fatigue-failure mechanisms is critical for the development of fatigue-resistant structural materials. Here we report a high-entropy alloy with enhanced fatigue life by ductile-transformable multicomponent B2 precipitates. Its cyclic-deformation mechanisms are revealed by real-time in-situ neutron diffraction, transmission-electron microscopy, crystal-plasticity modeling, and Monte-Carlo simulations. Multiple cyclic-deformation mechanisms, including dislocation slips, precipitation strengthening, deformation twinning, and reversible martensitic phase transformation, are observed in the studied high-entropy alloy. Its improved fatigue performance at low strain amplitudes, i.e., the high fatigue-crack-initiation resistance, is attributed to the high elasticity, plastic deformability, and martensitic transformation of the B2-strengthening phase. This study shows that fatigue-resistant alloys can be developed by incorporating strengthening ductile-transformable multicomponent intermetallic phases.
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