High-pressure operation through high strength linepipe reduces long distance transportation cost of natural gas. In order to maximize the cost reduction, X120 UOE pipe has been developed. Low C-Mo-B steel with fine-grained lower bainite (LB) microstructure realizes high strength, excellent low temperature toughness and good weldability. The technology was verified in small-scale commercial production or “mini-rolls”. Suitability for use as linepipe was demonstrated through an extensive development program that covers burst test, fracture toughness evaluation, girth welding technology, etc. A demonstration line was successfully constructed using the pipes manufactured in the “mini-rolls”.
The crack arrestability for high strength line pipe steels with tensile strength of 650 to 850 MPa was evaluated using precrack DWTT (pc-DWTT). Moreover, the effects of microstructure and texture on pc-DWTT energy were investigated. The pc-DWTT energy was remarkably affected by tensile strength. The pc-DWTT energy of ferrite and bainite/martensite dual phase steels was much higher than that of bainite single phase steels in comparison with the same tensile strength. The {100} plane is a cleavage plane in iron, so the brittle crack mainly propagates along the {100} plane. Bainte single phase steels indicated a high intensity of the {100} on the plane rotated 40° from the rolling plane with the axis of the rolling direction. On the other hand, ferrite and bainite/martensite dual phase steels indicated not only a high intensity of the {100} plane rotated 40° from the rolling plane, but also a high intensity of the {100} plane parallel to the rolling plane. Slant fracture could be easily formed by the high intensity of the {100} on the plane rotated 40° from the rolling plane if local brittle areas such as martensite and austenite constituent (M-A constituent), which became the initiation point of brittle fracture, existed. In contrast, separation tended to be formed by the high intensity of the {100} plane parallel to the rolling plane that was caused by the formation of ferrite and bainte/martensite dual phase microstructure. Thus, pc-DWTT energy and shear area were remarkably affected by microstructure and texture. Therefore, to control microstructure and texture is vay important for the improvement of pc-DWTT properties.
New X80 UOE pipe manufacturing technology has been developed to attain excellent CTOD properties in HAZ. In the new steel pipe, the HAZ microstructure near the weld fusion line is refined by utilizing the strong suppression of austenite grain growth as well as the formation of intragranular ferrite (IGF). The IGF grows radially from oxides in the same way as in Ti-O steel. The suppression of austenite grain growth is due to the pinning effect by fine particles including ultra fine oxides. As these oxides dispersed in the steels are chemically stable even near the fusion line, the microstructure can be refined. In addition, it is also necessary to suppress the formation of coarse grain boundary ferrite (GBF) near the weld fusion line in order to obtain excellent CTOD properties. So, it was found that the increase of boron addition in weld metal is effective to suppress the formation of coarse GBF near the weld fusion line because boron atoms diffuse into prior austenite grain boundaries near the fusion line from the molten pool during welding. This paper describes new technology for improving CTOD properties in HAZ. The X80 UOE pipe manufactured on a large scale and exhibited excellent CTOD properties at −30°.
In strain-based design, the overmatch condition in the girth weld portion primarily must be maintained. The pipes may also be required to have a low yield to tensile (Y/T) ratio and a high uniform elongation (U.EL) in the longitudinal direction to achieve a high compressive buckling strain. However, change in the mechanical properties by heating during coating treatment has not been paid attention so much. Furthermore, how much the mechanical properties change is affected by production conditions is unclear. This study aims to clarify firstly the relation between the mechanical properties (Y/T ratio, U.EL etc.) and the microstructure and secondly the change in mechanical properties by thermal coating treatment. The Y/T ratio and U.EL are affected by the volume fraction of ferrite and the secondary phase, which are changed by thermomechanical control processing (TMCP) conditions. For example, use of dual phase microstructure is very effective for decreasing the Y/T ratio and increasing the U.EL as the pipe. On the other hand, yield strength (YS) rises and the U.EL does not change after coating. The increase in the YS after coating is influenced by the microstructure and TMCP conditions. Resultantly, dependence of the Y/T ratio on the microstructure and TMCP conditions is reduced for line pipes after thermal coating treatment.
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